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Synthesis of (E)-2-chlorovinyltellurium trichloride and (E,E)-bis(2-chlorovinyl) ditelluride

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Abstract

The reaction of tellurium tetrachloride with acetylene in CCl4 at atmospheric pressure and ambient temperature affords earlier unknown (E)-2-chlorovinyltellurium trichloride in 30% yield, whose reduction with sodium bisulfite gives (E,E)-bis(2-chlorovinyl) ditelluride in 64% yield.

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Authors and Affiliations

  1. A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, 1 ul. Favorskogo, 664033, Irkutsk, Russian Federation

    V. A. Potapov, M. V. Musalova & S. V. Amosova

Authors
  1. V. A. Potapov
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  2. M. V. Musalova
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  3. S. V. Amosova
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Correspondence to S. V. Amosova.

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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 1, pp. 201–202, January, 2012.

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Potapov, V.A., Musalova, M.V. & Amosova, S.V. Synthesis of (E)-2-chlorovinyltellurium trichloride and (E,E)-bis(2-chlorovinyl) ditelluride. Russ Chem Bull 61, 204–205 (2012). https://doi.org/10.1007/s11172-012-0028-3

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  • DOI: https://doi.org/10.1007/s11172-012-0028-3

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