Skip to main content
SpringerLink
Log in

Competing ferro- and antiferromagnetic interactions in (manganese,sodium)phenylsilsesquioxane with metal oxide fragments

  • Brief Communications
  • Published:
Russian Chemical Bulletin Aims and scope

Abstract

Magnetic measurements of individual (manganese,sodium)phenylsilsesquioxane containing eight MnII ions were performed. The magnetic arrangement of manganese ions in this cage-like compound was investigated. The magnetic moment of the cage molecule equals 21 μB (at 300 K), that is a consequence of the mutual antiferromagnetic compensation of four MnII ions, whereas the other four MnII ions have aligned spins. Hence, this metallasiloxane is a promising compound for the chemical design of molecular nanomagnets. At low temperatures, the antiferromagnetic coupling causes a decrease in the effective magnetic moment (to 16 μB at 40 K).

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

References

  1. T. Lis, Acta Crystallogr., 1980, 636, 2042.

    Google Scholar 

  2. R. Sessoli, H.-L. Tsai, A. R. Schake, S. Wang, J. B. Vincent, K. Folting, D. Gatteschi, G. Christou, D. N. Hendrickson, J. Am. Chem. Soc., 1993, 115, 1804.

    Article  CAS  Google Scholar 

  3. R. Sessoli, D. Gatteschi, A. Caneschi, M. A. Novak, Nature, 1993, 365, 141.

    Article  CAS  Google Scholar 

  4. M. A. Novak, R. Sessoli, A. Caneschi, D. Gatteschi, J. Magn. Magn. Mater., 1995, 146, 211.

    Article  CAS  Google Scholar 

  5. S. M. J. Aubin, N. R. Dilley, L. Pardi, J. Krzystek, M. W. Wemple, L. C. Brunel, M. B. Maple, G. Christou, D. N. Hendrickson, J. Am. Chem. Soc., 1998, 120, 4991.

    Article  CAS  Google Scholar 

  6. S. M. J. Aubin, Z. Sun, L. Pardi, J. Krzystek, K. Folting, L. C. Brunel, A. L. Rheingold, G. Christou, D. N. Hendrickson, Inorg. Chem., 1999, 38, 5329.

    Article  CAS  Google Scholar 

  7. G. Christou, D. Gatteschi, D. N. Hendrickson, R. Sessoli, MRS Bull., 2000, 11, 66.

    Article  Google Scholar 

  8. H. J. Eppley, H.-L. Tsai, N. de Vries, K. Folting, G. Christou, D. N. Hendrickson, J. Am. Chem. Soc., 1995, 117, 301.

    Article  CAS  Google Scholar 

  9. H. J. Eppley, S. Wang, H.-L. Tsai, S. M. J. Aubin, K. Folting, W. E. Streib, D. N. Hendrickson, G. Christou, Mol. Cryst. Liq. Cryst., 1995, 274, 159; H.-L. Tsai, H. J. Eppley, N. de Vries, K. Folting, G. Christou, D. N. Hendrickson, Mol. Cryst. Liq. Cryst., 1995, 274, 167.

    Article  Google Scholar 

  10. S. M. Aubin, S. J. Spagna, H. J. Eppley, R. E. Sager, K. Folting, G. Christou, D. N. Hendrickson, Mol. Cryst. Liq. Cryst., 1997, 305, 181.

    Article  CAS  Google Scholar 

  11. H. J. Eppley, S. M. J. Aubin, M. W. Wemple, D. M. Adams, H.-L. Tsai, V. A. Grillo, S. L. Castro, Z. Sun, K. Folting, J. C. Huffman, D. N. Hendrickson, G. Christou, Mol. Cryst. Liq. Cryst., 1997, 305, 167.

    Article  CAS  Google Scholar 

  12. P. D. W. Boyd, Q. Li, J. B. Vincent, K. Folting, H.-R. Chang, W. E. Streib, J. C. Huffman, G. Christou, D. N. Hendrickson, J. Am. Chem. Soc., 1988, 110, 8537.

    Article  CAS  Google Scholar 

  13. A. R. Schake, H.-L. Tsai, N. de Vries, R. J. Webb, K. Folting, D. N. Hendrickson, G. Christou, J. Chem. Soc., Chem. Commun., 1992, 181.

  14. R. Sessoli, H.-L. Tsai, A. R. Schake, S. Wang, J. B. Vincent, K. Folting, D. Gatteschi, G. Christou, D. N. Hendrickson, J. Am. Chem. Soc., 1993, 115, 1804.

    Article  CAS  Google Scholar 

  15. S. M. J. Aubin, N. R. Dilley, L. Pardi, J. Krzystek, M. W. Wemple, L. C. Brunel, M. B. Maple, G. Christou, D. N. Hendrickson. J. Am. Chem. Soc., 1998, 120, 4991.

    Article  CAS  Google Scholar 

  16. D. Ruiz, Z. Sun, S. M. J. Aubin, E. Rumberger, C. Incarvito, K. Folting, G. Christou, D. N. Hendrickson, Mol. Cryst. Liq. Cryst., 1999, 335, 413.

    Article  Google Scholar 

  17. M. Soler, W. Wernsdorfer, K. Folting, M. Pink, G. Christou, J. Am. Chem. Soc., 2004, 126, 2156.

    Article  CAS  Google Scholar 

  18. C. Boskovic, M. Pink, J. C. Huffman, D. N. Hendrickson, G. Christou, J. Am. Chem. Soc., 2001, 123, 9914.

    Article  CAS  Google Scholar 

  19. G. Christou, D. Gatteschi, D. N. Hendrickson, Single-Molecule Magnets, MRS Bulletin 25, 2000, 66.

  20. A. N. Bilyachenko, M. S. Dronova, A. A. Korlyukov, M. M. Levitskii, M. Yu. Antipin, B. G. Zavin, Izv. Akad. Nauk, Ser. Khim., 2010, 1736 [Russ. Chem. Bull., Int. Ed., 2011, 60, No. 8].

    Google Scholar 

  21. L. F. Heidt, G. F. Koster, A. M. Jonson, J. Am. Chem. Soc., 1958, 80, 6471.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    M. M. Levitsky, A. N. Bilyachenko & E. S. Shubina

  2. M. V. Lomonosov Moscow State Academy of Fine Chemical Technology, 86 prosp. Vernadskogo, 119571, Moscow, Russian Federation

    M. S. Dronova & A. D. Kirilin

  3. Institute of Problems of Chemical Physics, Russian Academy of Sciences, 1 prosp. Akad. Semenova, 142432, Chernogolovka, Moscow Region, Russian Federation

    A. I. Dmitriev & R. B. Morgunov

Authors
  1. M. M. Levitsky
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. N. Bilyachenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. M. S. Dronova
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. A. I. Dmitriev
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. R. B. Morgunov
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. E. S. Shubina
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. A. D. Kirilin
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to M. M. Levitsky.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 1, pp. 197–200, January, 2012.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Levitsky, M.M., Bilyachenko, A.N., Dronova, M.S. et al. Competing ferro- and antiferromagnetic interactions in (manganese,sodium)phenylsilsesquioxane with metal oxide fragments. Russ Chem Bull 61, 200–203 (2012). https://doi.org/10.1007/s11172-012-0027-4

Download citation

  • Received:

  • Revised:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11172-012-0027-4

Key words

Search

Navigation