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Synthesis and structure of homochiral polymeric praseodymium tartrate

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Abstract

The homochiral metal-organic coordination polymer of the composition [{Pr(H2O)2}2-(d-tart)3]·H2O was synthesized by heating an aqueous solution of praseodymium(III) chloride and d-tartaric acid (d-H2tart) in the presence of KOH. The crystal structure of the polymer was determined by X-ray crystallography and confirmed by IR spectroscopy, thermogravimetry, and elemental analysis.

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Authors and Affiliations

  1. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3 prosp. Akad. Lavrentieva, 630090, Novosibirsk, Russian Federation

    M. S. Zavakhina, D. G. Samsonenko, D. N. Dybtsev & V. P. Fedin

  2. Novosibirsk State University, 2 ul. Pirogova, 630090, Novosibirsk, Russian Federation

    M. S. Zavakhina, M. P. Yutkin, D. G. Samsonenko & V. P. Fedin

  3. Division of the Advanced Materials Science, Pohang University of Science and Technology (POSTECH), San 31, Hyojadong, Pohang, 790-784, Republic of Korea

    M. P. Yutkin & D. N. Dybtsev

Authors
  1. M. S. Zavakhina
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  2. M. P. Yutkin
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  3. D. G. Samsonenko
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  4. D. N. Dybtsev
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  5. V. P. Fedin
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Corresponding author

Correspondence to V. P. Fedin.

Additional information

Dedicated to Academician of the Russian Academy of Sciences O. M. Nefedov on the occasion of his 80th birthday.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp. 2378–2381, November, 2011.

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Zavakhina, M.S., Yutkin, M.P., Samsonenko, D.G. et al. Synthesis and structure of homochiral polymeric praseodymium tartrate. Russ Chem Bull 60, 2425–2428 (2011). https://doi.org/10.1007/s11172-011-0373-7

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  • DOI: https://doi.org/10.1007/s11172-011-0373-7

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