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A novel efficient approach to heteronuclear triple-decker complexes of rare earth elements with phthalocyanines

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Abstract

A novel approach to heteroleptic heteronuclear rare earth metal(III) trisphthalocyaninates was proposed with the complexes [(15C5)4Pc]M*[(15C5)4Pc]M(Pc) as examples (15C5 is 15-crown-5, Pc2− is the phthalocyaninate dianion, and M* ≠ M = Yb and Y). Unsubstituted lanthanum bisphthalocyaninate, La(Pc)2, was used for the first time as a Pc2− donor in the synthesis of such complexes. This substantially increased the yields of the target heteronuclear complexes over the previous literature data.

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Authors and Affiliations

  1. A. N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, 31 Leninsky prosp., 119071, Moscow, Russian Federation

    A. Yu. Tsivadze, A. G. Martynov, M. A. Polovkova & Yu. G. Gorbunova

  2. N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 119991, Moscow, Russian Federation

    A. Yu. Tsivadze, A. G. Martynov, M. A. Polovkova & Yu. G. Gorbunova

Authors
  1. A. Yu. Tsivadze
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  2. A. G. Martynov
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  3. M. A. Polovkova
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  4. Yu. G. Gorbunova
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Corresponding author

Correspondence to Yu. G. Gorbunova.

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Dedicated to Academician of the Russian Academy of Sciences O. M. Nefedov on the occasion of his 80th birthday.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp. 2216–2220, November, 2011.

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Tsivadze, A.Y., Martynov, A.G., Polovkova, M.A. et al. A novel efficient approach to heteronuclear triple-decker complexes of rare earth elements with phthalocyanines. Russ Chem Bull 60, 2258–2262 (2011). https://doi.org/10.1007/s11172-011-0345-y

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  • DOI: https://doi.org/10.1007/s11172-011-0345-y

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