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Cage-like manganesephenylsiloxane with an unusual structure

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Abstract

A polyhedral (manganese,sodium)phenylsiloxane of the composition (C6H5SiO1,5)20(MnO)8(NaO0,5)12·2NaOH·15C2H5OH·11 H2O (the molecular formula is C150H214Mn8Na14O72Si20) was synthesized. This compound possesses the earlier undescribed shape of the cage and a rare combination of silanolate anions Si-O− and metalloxide fragments Mn-O-Mn in one structure. The coordination sphere of Mn ions is filled with silanolate anions, the O atoms in the fragments Mn-O-Si, Mn-O-Mn, and encapsulated molecules of water. The molecules of solvate ethanol are coordinated exclusively with Na+ cations and are not involved into coordination sphere of MnII ions.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    A. N. Bilyachenko, M. S. Dronova, A. A. Korlyukov, M. M. Levitsky, M. Yu. Antipin & B. G. Zavin

Authors
  1. A. N. Bilyachenko
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  2. M. S. Dronova
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  3. A. A. Korlyukov
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  4. M. M. Levitsky
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  5. M. Yu. Antipin
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  6. B. G. Zavin
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Corresponding author

Correspondence to M. M. Levitsky.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1735–1738, August, 2011.

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Bilyachenko, A.N., Dronova, M.S., Korlyukov, A.A. et al. Cage-like manganesephenylsiloxane with an unusual structure. Russ Chem Bull 60, 1762–1765 (2011). https://doi.org/10.1007/s11172-011-0260-2

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  • DOI: https://doi.org/10.1007/s11172-011-0260-2

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