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α-Nitroalkyl-ONN-azoxyfurazanes and some of their derivatives

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A reaction of aminofurazanes with 2,2-dimethyl-5-nitro-5-nitroso-1,3-dioxane in the presence of dibromoisocyanurate furnished (2,2-dimethyl-5-nitro-1,3-dioxan-5-yl-ONN-azoxy)-furazanes. Their reactions with AcCl/MeOH and subsequent transformations led to the first members of substituted mononitroalkyl- and (polynitroalkyl-ONN-azoxy)furazanes, viz., 3-(nitromethyl-ONN-azoxy)-4-nitrofurazane, 3-(dinitromethyl-ONN-azoxy)-4-nitrofurazane, 3-(trinitromethyl-ONN-azoxy)-4-nitrofurazane, and some of their derivatives and analogs.

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Authors and Affiliations

  1. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation

    O. A. Lukýanov, G. V. Pokhvisneva, T. V. Ternikova, N. I. Shlykova & M. E. Shagaeva

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  1. O. A. Lukýanov
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  2. G. V. Pokhvisneva
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  3. T. V. Ternikova
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  4. N. I. Shlykova
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  5. M. E. Shagaeva
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Correspondence to O. A. Lukýanov.

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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1678–1686, August, 2011.

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Lukýanov, O.A., Pokhvisneva, G.V., Ternikova, T.V. et al. α-Nitroalkyl-ONN-azoxyfurazanes and some of their derivatives. Russ Chem Bull 60, 1703–1711 (2011). https://doi.org/10.1007/s11172-011-0254-0

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  • DOI: https://doi.org/10.1007/s11172-011-0254-0

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