Skip to main content
SpringerLink
Log in

Synthesis of bimetallic cage-like metalloorganosiloxanes from polymeric metallosiloxanes

  • Full Articles
  • Published:
Russian Chemical Bulletin Aims and scope

Abtract

A new approach to the synthesis of the cage-like metalloorganosiloxanes (MOS) was developed. Unlike existing schemes for the synthesis of the cage-like MOS from monomeric structural units, regular polyhedral structures were formed from irregular polymeric MOS by their reaction with sodium phenylsilanolate. Efficiency of the method suggested was confirmed by directed synthesis of the earlier described bimetallic cage-like (CuII,Na)- and (FeIII,Na)-phenylsiloxanes in 69 and 47% yields, respectively. Compounds that obtained were identified by destructive trimethylsilylation, GPC, 1H NMR, and X-ray crystallography.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. M. M. Levitskii, B. G. Zavin, A. N. Bilyachenko, Usp. Khim., 2007, 76, 907 [Russ. Chem. Bull. (Engl. Transl.), 2007, 76].

    Google Scholar 

  2. M. G. Voronkov, V. P. Mileshkevich, Yu. A. Yuzhelevskii, Siloksanovaya svyaz’ [Siloxane Bond], Nauka, Novosibirsk, 1976 (in Russian).

    Google Scholar 

  3. M. G. Voronkov, E. A. Maletina, V. K. Roman, Geterosiloxany [Heterosiloxanes], Nauka, Novosibirsk, 1984 (in Russian).

    Google Scholar 

  4. A. A. Zhdanov, N. V. Sergienko, E. S. Trankina, Russ. Khim. Zh., 2001, 45, 44 [Mendeleev Chem. J. (Engl. Transl.), 2001, 45].

    CAS  Google Scholar 

  5. M. M. Levitskii, S. P. Knyazev, A. N. Bilyachenko, B. G. Zavin, Tez. dokl. XX simpoziuma “Sovremennaya khimicheskaya fizika” [Abstracts of the XX Symposium “Modern Chemical Physics”] (September 15–26, 2008, Burevestnik MSU Guest house, Tuapse), p. 11 (in Russian).

  6. A. A. Zhdanov, N. V. Sergienko, E. S. Trankina, Izv. Akad. Nauk, Ser. Khim., 1998, 2530 [Russ. Chem. Bull. (Engl. Transl.), 1998, 2448].

  7. I. L. Dubchak, V. E. Shklover, A. A. Zhdanov, Yu. T. Struchkov, Zh. Strukt. Khim, 1980, 21, 103 [J. Struct. Chem. USSR (Engl. Transl.), 1980, 21].

    CAS  Google Scholar 

  8. V. A. Igonin, S. V. Lindeman, Yu. T. Struchkov, O. I. Shchegolikhina, A. A. Zhdanov, Yu. A. Molodtsova, I. V. Razumovskaya, Metalloorg. Khim, 1991, 4, 1355 [Organomet. Chem. USSR (Engl. Transl.), 1991, 4].

    CAS  Google Scholar 

  9. A. N. Bilyachenko, A. A. Korlyukov, M. M. Levitskii, M. Yu. Antipin, B. G. Zavin, Izv. Akad. Nauk, Ser. Khim., 2007, 522 [Russ. Chem. Bull., Int. Ed., 2007, 46].

  10. B. G. Zavin, N. V. Sergienko, E. V. Gorodnichev, V. D. Myakushev, A. A. Korlyukov, M. Yu. Antipin, Mendeleev Commun., 2005, 15, 245.

    Article  Google Scholar 

  11. A. A. Zhdanov, O. I. Shchegolikhina, Yu. A. Molodtsova, T. V. Strelkova. Dokl. Akad. Nauk, 1992, 325, 1186.

    Google Scholar 

  12. M. M. Levitskii, A. I. Kokorin, V. V. Smirnov, N. V. Karpilovskaya, A. V. Kudryashov, S. M. Nevskaya, E. N. Golubeva, Izv. Akad. Nauk, Ser. Khim., 1998, 1946 [Russ. Chem. Bull. (Engl. Transl.), 1998, 47, 1892].

    Google Scholar 

  13. A. A. Zhdanov, K. A. Andrianov, M. M. Levitskii, Vysokomolekulyar. Soedin., 1976, 18, A, 2264 [Polym. Sci. USSR (Engl. Transl.), 1976, 18A].

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    B. G. Zavin, N. V. Sergienko, N. V. Cherkun, A. N. Bilyachenko, O. M. Starikova, A. A. Korlyukov, M. S. Dronova, M. M. Levitskii & G. I. Timofeeva

Authors
  1. B. G. Zavin
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. N. V. Sergienko
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. N. V. Cherkun
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. A. N. Bilyachenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. O. M. Starikova
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. A. A. Korlyukov
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. M. S. Dronova
    View author publications

    You can also search for this author in PubMed Google Scholar

  8. M. M. Levitskii
    View author publications

    You can also search for this author in PubMed Google Scholar

  9. G. I. Timofeeva
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to B. G. Zavin.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1621–1624, August, 2011.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Zavin, B.G., Sergienko, N.V., Cherkun, N.V. et al. Synthesis of bimetallic cage-like metalloorganosiloxanes from polymeric metallosiloxanes. Russ Chem Bull 60, 1647–1650 (2011). https://doi.org/10.1007/s11172-011-0246-0

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11172-011-0246-0

Key words

Search

Navigation