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Neodymium(iii) and dysprosium(iii) naphthalene hydride complexes

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Abstract

Reactions of neodymium and dysprosium diiodide hydrides LnI2H with lithium naphthalenide in THF furnished heterobimetallic naphthalene hydride clusters (C10H8)3Ln5Li5H14 (Ln = Nd, Dy). Treatment of the latter with hexamethyldisilazane in THF leads to the removal of lithium in the form of LiN(SiMe3)2 and the formation of compounds of the composition (C10H8)3Ln5H9 (Ln = Nd, Dy). All the clusters obtained were isolated as black pyrophoric powders insoluble in THF and other organic solvents. Reactions of (C10H8)3Nd5Li5H14 and (C10H8)3Nd5H9 with cyclopentadiene lead to Cp3Nd(THF).

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Authors and Affiliations

  1. G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, 49 ul. Tropinina, 603950, Nizhny Novgorod, Russian Federation

    M. E. Burin, A. A. Logunov, V. I. Faerman & M. N. Bochkarev

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  1. M. E. Burin
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  2. A. A. Logunov
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  3. V. I. Faerman
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  4. M. N. Bochkarev
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Correspondence to M. N. Bochkarev.

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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1566–1569, August, 2011.

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Burin, M.E., Logunov, A.A., Faerman, V.I. et al. Neodymium(iii) and dysprosium(iii) naphthalene hydride complexes. Russ Chem Bull 60, 1591–1594 (2011). https://doi.org/10.1007/s11172-011-0237-1

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  • DOI: https://doi.org/10.1007/s11172-011-0237-1

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