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New conformer of 2,4,6,8,10,12-hexanitro-2,4,6,8,10,12-hexaazaisowurtzitane (CL-20). Crystal and molecular structures of the CL-20 solvate with glyceryl triacetate

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Abstract

Crystallization of CL-20 in different plasticizers (gyceryl triacetate and diethyleneglycol dinitrate) was studied. IR spectra of the crystals obtained under various conditions, as a rule, do not correspond to the spectra of known modifications. Crystal and molecular structures of the CL-20 solvate with glyceryl triacetate were studied. A new stable conformer of the CL-20 molecule was discovered.

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Authors and Affiliations

  1. Institute of Problems of Chemical Physics, Russian Academy of Sciences, 1 prosp. Akad. Semenova, 142432, Chernogolovka, Moscow Region, Russian Federation

    S. M. Aldoshin, Z. G. Aliev, T. K. Goncharov & D. V. Korchagin

  2. Soyuz Federal Center of Dual Technologies, 42 ul. Zhukova, 140090, Dzerzhinskii, Moscow Region, Russian Federation

    Yu. M. Milekhin & N. I. Shishov

Authors
  1. S. M. Aldoshin
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  2. Z. G. Aliev
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  3. T. K. Goncharov
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  4. D. V. Korchagin
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  5. Yu. M. Milekhin
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  6. N. I. Shishov
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Corresponding author

Correspondence to Z. G. Aliev.

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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 7, pp. 1372–1378, July, 2011.

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Aldoshin, S.M., Aliev, Z.G., Goncharov, T.K. et al. New conformer of 2,4,6,8,10,12-hexanitro-2,4,6,8,10,12-hexaazaisowurtzitane (CL-20). Crystal and molecular structures of the CL-20 solvate with glyceryl triacetate. Russ Chem Bull 60, 1394–1400 (2011). https://doi.org/10.1007/s11172-011-0209-5

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  • DOI: https://doi.org/10.1007/s11172-011-0209-5

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