Skip to main content
SpringerLink
Log in

Sorbents based on calix[4]arenes for extraction of technetium(vii) from acidic and alkaline media

  • Brief Communications
  • Published:
Russian Chemical Bulletin Aims and scope

Abstract

Sorption of TcVII from solutions of various compositions with new sorbents prepared by the noncovalent immobilization of (thia)calix[4]arenes on the Amberlite XAD-7™ support was studied. The sorbents studied efficiently extract technetium(vii) from both acidic and alkaline media. The sorption capacity of the sorbent with thiacalix[4]arene groups is superior to that of the sorbents with calix[4]arene groups and several times higher than that of the sorbents previously proposed for the sorption of TcVII. Technetium(vii) is sorbed by this sorbent as 1: 1 and 1: 2 thiacalix[4]arene—NH4TcO4 and 1: 1 and 1: 2 thiacalix[4]arene—NaTcO4 complexes.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

References

  1. N. N. Popova, I. G. Tananaev, S. I. Rovnyi, B. F. Myasoedov, Usp. Khim., 2003, 72, 115 [Russ. Chem. Rev. (Engl. Transl.), 2003, 72].

    Google Scholar 

  2. C. D. Gutsche, Calixarenes Revisited, Monographs in Supramolecular Chemistry, Ed. J. F. Stoddart, RSC, London, 1998, p 233.

    Google Scholar 

  3. I. S. Antipin, I. G. Tananaev, A. I. Konovalov, Zh. Vseros. Khim. o-va im. D. I. Mendeleeva [J. All-Russia D. I. Mendeleev Chemical Society], 2005, 69, No. 2, 80 (in Russian).

    Google Scholar 

  4. I. S. Antipin, S. E. Solovieva, I. I. Stoikov, I. S. Vershinina, G. A. Pribylova, I. G. Tananaev, B. F. Myasoedov, Izv. Akad. Nauk, Ser. Khim., 2004, 124 [Russ. Chem. Bull., Int. Ed., 2004, 53, 127].

    Google Scholar 

  5. M. A. McKervey, M.-J. Schwing-Weill, F. Arnaud-Neu, in Comperehensive Supramolecular Chemistry, Ed. G. W. Gokel, Pergamon, Oxford, 1996, 1, 537.

    Google Scholar 

  6. R. Ludwig, Fresenius, J. Anal. Chem., 2000, 367, 103.

    CAS  Google Scholar 

  7. A. Arduini, E. Ghidini, A. Ponchini, R. Ungaro, G. D. Andreetti, G. Calestani, F. Ugozzoli, J. Incl. Phenom., 1988, 6, 119.

    Article  CAS  Google Scholar 

  8. P. D. Beer, M. G. B. Drew, Ph. A. Gale, Ph. B. Leeson, M. I. Ogden, J. Chem. Soc., Dalton Trans., 1994, 23, 3479.

    Article  Google Scholar 

  9. S. E. Solovieva, M. Grüner, A. O. Omran, A. T. Gubaidullin, I. A. Litvinov, W. D. Habicher, I. S. Antipin, A. I. Konovalov, Izv. Akad. Nauk, Ser. Khim., 2005, 2041 [Russ. Chem. Bull., Int. Ed., 2005, 54, 2104].

    Google Scholar 

  10. K. Haupt, Analyst, 2001, 126, 747.

    Article  CAS  Google Scholar 

  11. C. F. Poole, Trends. Anal. Chem., 2003, 22, 362.

    Article  CAS  Google Scholar 

  12. G. Limousin, J.-P. Gaudet, L. Charlet, S. Szenknect, V. Barthes, M. Krimissa, Appl. Geochem., 2007, 22, 249.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. A. N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, building 4, 31 Leninsky prosp., 119991, Moscow, Russian Federation

    N. N. Popova & I. G. Tananaev

  2. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    V. P. Morgalyuk

  3. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center of the Russian Academy of Sciences, 8 ul. Arbuzova, 420088, Kazan, Russian Federation

    S. E. Solovieva, E. V. Popova & I. S. Antipin

Authors
  1. N. N. Popova
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. V. P. Morgalyuk
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. I. G. Tananaev
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. S. E. Solovieva
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. E. V. Popova
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. I. S. Antipin
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to N. N. Popova.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Popova, N.N., Morgalyuk, V.P., Tananaev, I.G. et al. Sorbents based on calix[4]arenes for extraction of technetium(vii) from acidic and alkaline media. Russ Chem Bull 60, 175–178 (2011). https://doi.org/10.1007/s11172-011-0026-x

Download citation

  • Received:

  • Revised:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11172-011-0026-x

Key words

Search

Navigation