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Supramolecular systems based on 1-alkyl-4-aza-1-azoniabicyclo[2.2.2]octane bromides

Abstract

The aggregation in aqueous solutions of alkylated 1,4-diazabicyclo[2.2.2]octanes of various hydrophobicity and their adsorption at the water-air interface were studied by tensiometry, conductometry, potentiometry, viscosimetry, and ESR spectroscopy. The parameters of adsorption, critical micelle concentrations, concentrations of free counterions (bromide ions), and degree of binding of the counterions with micelles were determined. The intensification of the micelle formation ability of the surfactants with an elongation of the alkyl fragment was shown. The effective radii of ensembles of the hexadecyl and octadecyl derivatives were determined by the dynamic light scattering method. A relationship between the concentration dependences of the size of micelles and their shape was established.

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Correspondence to E. P. Zhil’tsova.

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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1699–1706, September, 2010.

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Pashirova, T.N., Zhil’tsova, E.P., Kashapov, R.R. et al. Supramolecular systems based on 1-alkyl-4-aza-1-azoniabicyclo[2.2.2]octane bromides. Russ Chem Bull 59, 1745–1752 (2010). https://doi.org/10.1007/s11172-010-0307-9

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Key words

  • alkylated 1,4-diazabicyclo[2.2.2]octanes
  • adsorption
  • association
  • critical micelle concentration
  • ensemble radius
  • micelle shape