Abstract
Three dialkoxysilanes with fluorine-containing groups were synthesized: methyl(3,3,3-trifluoropropyl)dimethoxysilane, methyl(3,3,3-trifluoropropyl)bis(2,2,2-trifluoroethoxy)silane, and methyl(2,2,2-trifluoro-1-trifluoromethylethoxymethyl)bis(2,2,2-trifluoro-1-trifluoro-methylethoxy)silane. It was found by IR and 29Si NMR spectroscopies that (3-aminopropyl)-triethoxysilane forms complexes with the indicated compounds, which are hydrolyzed in the presence of air moisture to form films of high optical quality.
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 5, pp. 990–997, May, 2009.
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Ladilina, E.Y., Lyubova, T.S., Semenov, V.V. et al. Fluorine-containing dialkoxysilanes. The formation of complexes with aminopropyltriethoxysilane and production of transparent films. Russ Chem Bull 58, 1015–1022 (2009). https://doi.org/10.1007/s11172-009-0130-3
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DOI: https://doi.org/10.1007/s11172-009-0130-3