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First synthesis of 1,5-diazabicyclo[3.1.0]hexane complexes with cadmium salts

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Abstract

Complexes of bicyclic diaziridines 6,6′-bi(1,5-diazabicyclo[3.1.0]hexane) (L 1) and 6-(4-methoxyphenyl)-1,5-diazabicyclo[3.1.0]hexane (L 2) with the salts Cd(NO3)2 · 4H2O and Cd(ClO4)2 · 6H2O have been synthesized. The fact of complexation has been established by cyclic voltammetry. The crystal structure of complex L 1 with Cd(NO3)2 (the coordination number of cadmium is 8) has been studied by X-ray diffraction.

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Authors and Affiliations

  1. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation

    Yu. S. Syroeshkina, L. L. Fershtat, M. A. Syroeshkin, V. V. Kuznetsov & N. N. Makhova

  2. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    K. A. Lyssenko

Authors
  1. Yu. S. Syroeshkina
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  2. L. L. Fershtat
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  3. M. A. Syroeshkin
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  4. V. V. Kuznetsov
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  5. K. A. Lyssenko
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  6. N. N. Makhova
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Corresponding author

Correspondence to N. N. Makhova.

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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 5, pp. 977–981, May, 2009.

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Syroeshkina, Y.S., Fershtat, L.L., Syroeshkin, M.A. et al. First synthesis of 1,5-diazabicyclo[3.1.0]hexane complexes with cadmium salts. Russ Chem Bull 58, 1002–1006 (2009). https://doi.org/10.1007/s11172-009-0128-x

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  • DOI: https://doi.org/10.1007/s11172-009-0128-x

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