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Synthesis of metallacarborane triple-decker complexes with the bridging diborolyl ligand

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Abstract

Triple-decker complexes CpCo(μ-1,3-C3B2Me5)M(η-7,8-C2B9H11) (M = Rh (3), Ir (4)) were synthesized by the reaction of [CpCo(μ-1,3-C3B2Me5)MBr2]2 (M = Rh, Ir) with Tl[TlC2B9H11]. The structure of 3 was established by X-ray diffraction analysis.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    D. V. Muratov, A. S. Romanov, P. V. Petrovskii, Z. A. Starikova & A. R. Kudinov

Authors
  1. D. V. Muratov
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  2. A. S. Romanov
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  3. P. V. Petrovskii
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  4. Z. A. Starikova
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  5. A. R. Kudinov
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Corresponding author

Correspondence to A. R. Kudinov.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 5, pp. 944–946, May, 2009.

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Muratov, D.V., Romanov, A.S., Petrovskii, P.V. et al. Synthesis of metallacarborane triple-decker complexes with the bridging diborolyl ligand. Russ Chem Bull 58, 968–970 (2009). https://doi.org/10.1007/s11172-009-0124-1

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  • DOI: https://doi.org/10.1007/s11172-009-0124-1

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