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Synthesis of μ-diborolyl triple-decker complexes [CpCo(1,3-C3B2Me5)Ru(arene)]+

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Abstract

Cationic triple-decker complexes [CpCo(1,3-C3B2Me5)Ru(arene)]PF6 (arene is benzene (2a), p-cymene (2b)) with a bridging diborolyl ligand were synthesized by the reaction of the sand-wich anion [CpCo(1,3-C3B2Me5)]− (1) with [(arene)RuCl2]2. The structure of [2b]PF6 was confirmed by X-ray diffraction analysis.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    D. V. Muratov, A. S. Romanov, P. V. Petrovskii, M. Yu. Antipin & A. R. Kudinov

  2. Department of Natural Sciences, New Mexico Highlands University, Las Vegas, NM, 87701, USA

    A. S. Romanov & M. Yu. Antipin

Authors
  1. D. V. Muratov
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  2. A. S. Romanov
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  3. P. V. Petrovskii
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  4. M. Yu. Antipin
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  5. A. R. Kudinov
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Corresponding author

Correspondence to A. S. Romanov.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 5, pp. 941–943, May, 2009.

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Muratov, D.V., Romanov, A.S., Petrovskii, P.V. et al. Synthesis of μ-diborolyl triple-decker complexes [CpCo(1,3-C3B2Me5)Ru(arene)]+ . Russ Chem Bull 58, 964–967 (2009). https://doi.org/10.1007/s11172-009-0123-2

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  • DOI: https://doi.org/10.1007/s11172-009-0123-2

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