Skip to main content
SpringerLink
Log in

Chemistry of vinylidene complexes

19. New heterometallic μ-vinylidene complexes with Re-M (M = Pd, Pt) bonds. Molecular structure of (η5-C5H5)(CO)RePt(μ-C=CHPh)(μ-CO)(Ph2PCH2PPh2)

  • Full Articles
  • Published:
Russian Chemical Bulletin Aims and scope

Abstract

The reactions of Cp(CO)2Re=C=CHPh (2) with M(PPh3)4 (M = Pd, Pt) gave the μ-vinylidene complexes Cp(CO)2RePd(μ-C=CHPh)(PPh3)2 (3) and Cp(CO)2RePt(μ-C=CHPh)(PPh3)2 (1), respectively. The substitution of Ph2PCH2PPh2 (dppm) for the PPh3 ligands in 1 resulted in the formation of Cp(CO)RePt(μ-C(1)=C(2)HPh)(μ-CO)(dppm) (4). The structure of complex 4 has been determined by single-crystal X-ray diffraction analysis. The structural and spectroscopic characteristics of complexes 1, 3, and 4 were compared with the corresponding parameters of the manganese-containing analogs Cp(CO)2MnPd(μ-C=CHPh)(PPh3)2 (5), Cp(CO)2MnPt(μ-C=CHPh)(PPh3)2 (6) and Cp(CO)2MnPt(μ-C=CHPh)(dppm) (7).

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. A. B. Antonova, O. S. Chudin, A. D. Vasiliev, N. I. Pavlenko, W. A. Sokolenko, A. I. Rubaylo, O. V. Semeikin, J. Organomet. Chem., 2009, 694, 127.

    Article  CAS  Google Scholar 

  2. A. B. Antonova, A. A. Jogansson, Usp. Khim., 1989, 58, 1197 [Russ. Chem. Rev. (Engl. Transl.), 1989, 58, 693].

    CAS  Google Scholar 

  3. M. I. Bruce, Chem. Rev., 1991, 91, 197.

    Article  CAS  Google Scholar 

  4. H. Werner, Angew. Chem., Int. Ed. Engl., 1990, 29, 1077.

    Article  Google Scholar 

  5. A. B. Antonova, Coord. Chem. Rev., 2007, 251, 1521.

    Article  CAS  Google Scholar 

  6. S. P. Gubin, G. Yu. Yurkov, N. A. Kataeva, Nanochastitsy blagorodnykh metallov i materialy na ih osnove [The nanoparticles of noble metals and materials based on these particles], Azbuka, Moscow, 2006, 154 pp. (in Russian).

    Google Scholar 

  7. S. P. Gubin, Yu. A. Koksharov, G. B. Khomutov, G. Yu. Yurkov, Usp. Khim., 2005, 74, 539 [Russ. Chem. Rev. (Engl. Transl.), 2005, 74].

    Google Scholar 

  8. N. E. Kolobova, L. L. Ivanov, O. S. Zhvanko, A. S. Batsanov, Yu. T. Struchkov, J. Organomet. Chem., 1985, 279, 419.

    Article  CAS  Google Scholar 

  9. A. N. Nesmeyanov, G. G. Aleksandrov, A. B. Antonova, K. N. Anisimov, N. E. Kolobova, Yu. T. Struchkov, J. Organomet. Chem., 1976, 110, C36.

    Article  CAS  Google Scholar 

  10. A. B. Antonova, N. E. Kolobova, P. V. Petrovsky, B. V. Lokshin, N. S. Obezyuk, J. Organomet. Chem., 1977, 137, 55.

    Article  CAS  Google Scholar 

  11. N. E. Kolobova, L. L. Ivanov, O. S. Zhvanko, P. V. Petrovskii, Izv. Akad. Nauk SSSR, Ser. Khim., 1981, 432 [Bull. Akad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.), 1981, 20].

  12. N. E. Kolobova, L. L. Ivanov, O. S. Zhvanko, G. G. Aleksandrov, Yu. T. Struchkov, J. Organomet. Chem., 1982, 228, 265.

    Article  CAS  Google Scholar 

  13. H. Werner, F. J. Garcia Alonso, H. Otto, K. Peters, H. G. von Schnering, Chem. Ber., 1988, 121, 1565.

    Article  CAS  Google Scholar 

  14. A. B. Antonova, S. V. Kovalenko, A. A. Johansson, N. A. Deykhina, E. D. Korniets, Yu. T. Struchkov, A. I. Yanovsky, Metalloorg. Khim., 1989, 2, 1014 [Organomet. Chem. USSR (Engl. Transl.), 1989, 2, 530].

    CAS  Google Scholar 

  15. A. A. Johansson, A. B. Antonova, N. A. Deykhina, D. A. Pogrebnyakov, N. I. Pavlenko, G. V. Burmakina, A. I. Rubaylo, P. V. Petrovskii, A. G. Ginzburg, Zh. Obshch. Khim., 1999, 69, 881 [Russ. J. Gen. Chem. (Engl. Transl.), 1999, 69, 847].

    Google Scholar 

  16. A. B. Antonova, Z. A. Starikova, N. A. Deykhina, D. A. Pogrebnyakov, A. I. Rubaylo, J. Organomet. Chem., 2007, 692, 1641.

    Article  CAS  Google Scholar 

  17. A. B. Antonova, S. V. Kovalenko, E. D. Korniyets, P. V. Petrovsky, G. R. Gulbis, A. A. Johansson, Inorg. Chim. Acta, 1985, 96, 1.

    Article  CAS  Google Scholar 

  18. A. B. Antonova, S. V. Kovalenko, A. A. Johansson, E. D. Kornyets, I. A. Sukhina, A. G. Ginzburg, P. V. Petrovskii, Inorg. Chim. Acta, 1991, 182, 49.

    Article  CAS  Google Scholar 

  19. F. M. Dolgushin, N. A. Deykhina, D. A. Pogrebnyakov, A. B. Antonova, Acta Cryst. E, 2001, E57, m541.

    Article  Google Scholar 

  20. A. D. Vasiliev, A. B. Antonova, O. S. Chudin, Acta Cryst. E, 2007, E63, m2097.

    Article  Google Scholar 

  21. D. A. Pogrebnyakov, Z. A. Starikova, N. I. Pavlenko, A. I. Rubaylo, W. A. Sokolenko, O. S. Chudin, A. B. Antonova, Izv. Akad. Nauk, Ser. Khim., 2002, 1235 [Russ. Chem. Bull., Int. Ed., 2002, 51, 1339].

    Google Scholar 

  22. N. E. Kolobova, A. B. Antonova, O. M. Khitrova, J. Organomet. Chem., 1978, 146, 17.

    Article  Google Scholar 

  23. O. S. Chudin, A. B. Antonova, N. I. Pavlenko, A. I. Rubaylo, W. A. Sokolenko, A. D. Vasiliev, O. V. Semeikin, Zh. Sibirskogo federalnogo universiteta. Khimiya, 2008, 1, 60 [J. Siberian Federal University. Chemistry (Engl. Transl.), 2008, 1, 60].

    Google Scholar 

  24. A. D. Vasiliev, O. S. Chudin, A. B. Antonova, Acta Cryst. E, 2007, E63, m2272.

    Article  Google Scholar 

  25. B. P. Birukov, Yu. T. Struchkov, Usp. Khim., 1970, 39, 1672 [Russ. Chem. Rev. (Engl. Transl.), 1970, 39].

    Google Scholar 

  26. J. Xiao, R. J. Puddephatt, Coord. Chem. Rev., 1995, 143, 457.

    Article  CAS  Google Scholar 

  27. A. A. Johansson, A. B. Antonova, N. I. Pavlenko, A. I. Rubaylo, J. Mol. Struct., 1997, 408/409, 329.

    Article  Google Scholar 

  28. N. E. Kolobova, A. B. Antonova, O. M. Khitrova, M. Yu. Antipin, Yu. T. Struchkov, J. Organomet. Chem., 1977, 137, 69.

    Article  CAS  Google Scholar 

  29. G. M. Dawkins, M. Green, J. C. Jeffery, C. Sambale, F. G. A. Stone, J. Chem. Soc., Dalton Trans., 1983, 499.

  30. R. E. Colborn, D. L. Davies, A. F. Dyke, S. A. R. Knox, K. A. Mead, A. G. Orpen, J. Chem. Soc., Dalton Trans., 1989, 1799.

  31. D. A. Valyaev, O. V. Semeikin, M. G. Peterleitner, Y. A. Borisov, V. N. Khrustalev, A. M. Mazhuga, E. V. Kremer, N. A. Ustynyuk, J. Organomet. Chem., 2004, 689, 3837.

    Article  CAS  Google Scholar 

  32. D. R. Coulson, in Inorganic Synthesis, Ed. F. A. Cotton, New York, McGraw Hill Book Company, 1972, vol. 13, p. 121.

    Chapter  Google Scholar 

  33. L. Malatesta, C. Caviello, J. Chem. Soc., 1958, 2323.

  34. G. M. Sheldrick, SADABS. Version 2.01, Bruker AXS Inc., Madison, Wisconsin, USA, 2004.

    Google Scholar 

  35. G. M. Sheldrick, SHELXTL. Version 6.10, Bruker AXS Inc., Madison, Wisconsin, USA, 2004.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Chemistry and Chemical Technology, Siberian Branch of the Russian Academy of Sciences, 42 ul. K. Marksa, 660049, Krasnoyarsk, Russian Federation

    A. B. Antonova, O. S. Chudin, N. I. Pavlenko, W. A. Sokolenko & A. I. Rubaylo

  2. Siberian Federal University, 79 Svobodny Prospect, 660041, Krasnoyarsk, Russian Federation

    A. I. Rubaylo, A. D. Vasiliev & V. V. Verpekin

  3. L. V. Kirensky Institute of Physics, Siberian Branch of the Russian Academy of Sciences Akademgorodok, 660036, Krasnoyarsk, Russian Federation

    A. D. Vasiliev

  4. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    O. V. Semeikin

Authors
  1. A. B. Antonova
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. O. S. Chudin
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. N. I. Pavlenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. W. A. Sokolenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. A. I. Rubaylo
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. A. D. Vasiliev
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. V. V. Verpekin
    View author publications

    You can also search for this author in PubMed Google Scholar

  8. O. V. Semeikin
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to A. B. Antonova.

Additional information

For Part 18, see Ref. 1.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 5, pp. 933–940, May, 2009.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Antonova, A.B., Chudin, O.S., Pavlenko, N.I. et al. Chemistry of vinylidene complexes. Russ Chem Bull 58, 955–963 (2009). https://doi.org/10.1007/s11172-009-0122-3

Download citation

  • Received:

  • Revised:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11172-009-0122-3

Key words

Search

Navigation