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Synthesis, dimerization, and oligomerization of 5-silaspiro[4.4]non-2-ene

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Abstract

Synthesis of 5-silaspiro[4.4]non-2-ene and its low-temperature anionic polymerization with the ring opening have been accomplished. A dimer and cyclic oligomers with higher degree of polymerization are predominantly formed under the action of BunLi in THF at −78 °C.

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Authors and Affiliations

  1. A. V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 29 Leninsky prosp., 119991, Moscow, Russian Federation

    N. V. Ushakov & E. Sh. Finkel’shtein

Authors
  1. N. V. Ushakov
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  2. E. Sh. Finkel’shtein
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Correspondence to N. V. Ushakov.

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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 5, pp. 923–925, May, 2009.

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Ushakov, N.V., Finkel’shtein, E.S. Synthesis, dimerization, and oligomerization of 5-silaspiro[4.4]non-2-ene. Russ Chem Bull 58, 944–947 (2009). https://doi.org/10.1007/s11172-009-0120-5

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  • DOI: https://doi.org/10.1007/s11172-009-0120-5

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