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Synthesis and properties of pentamethylmetallocene derivatives Cp*MCp (M = Ru, Fe). Crystal structure of the salt [CpRuC5Me4CH2 +OC6H2(NO2)3 -]

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Abstract

Photolysis of a solution of Cp*RuCp (1) in CF3CO2H generates salt [CpRu(C5Me4CH2)]-(O2CCF3)(2 • O2CCF3). The reaction of compound 1 with oleum at 20 °C through the intermediate dication [η5-(CH2C5Me4)Ru(μ:η5,ν5-C5H4C5H5)Ru(C5Me4CH2)-η6]2+ leads to the triply charged cation η7CH2)2C5Me3Ru(μη5,η5-C5H4C5H4)Ru(C5Me4CH2)-η6]3+. Synthesis of pentamethylmetallocene derivatives CpMC5Me4X (M = Ru, Fe; X = CHO, CH2OH, CH2An) has been accomplished. The reactions of 1-hydroxymethyl-2,3,4,5-tetramethylruthenocene with acids CF3CO2H, HBF4, CF3CO2H/NaB[C6H3(CF3)2]4, and picric acid C6H2(NO2)3OH afforded salts 2•X (X = CF3CO2, BF4, B[C6H3(CF3)2]4), and (2,3,4,5-tetram ethylruthenocenyl)methyl picrate [CpRu(C5Me4CH2)-η6][(C6H2(NO2)3O] (2•C6H2(NO2)3O). Structure of the latter was characterized by single crystal X-ray diffraction.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    A. Z. Kreindlin, P. V. Petrovskii, K. Yu. Suponitsky & Z. A. Starikova

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  1. A. Z. Kreindlin
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  2. P. V. Petrovskii
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  3. K. Yu. Suponitsky
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  4. Z. A. Starikova
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Correspondence to A. Z. Kreindlin.

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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 794-799, April, 2009.

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Kreindlin, A.Z., Petrovskii, P.V., Suponitsky, K.Y. et al. Synthesis and properties of pentamethylmetallocene derivatives Cp*MCp (M = Ru, Fe). Crystal structure of the salt [CpRuC5Me4CH2 +OC6H2(NO2)3 -]. Russ Chem Bull 58, 810–816 (2009). https://doi.org/10.1007/s11172-009-0099-y

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  • DOI: https://doi.org/10.1007/s11172-009-0099-y

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