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Effect of the medium on the reactivity of fullerene N60 with respect to the peroxide radicals RO2 ·. Chemiluminescence in the C60—AIBN—O2—C2H5Ph—PhH system

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Abstract

Chemiluminescence (CL), HLPC, and volumetry were used to demonstrate that fullerene N60 exerts no inhibiting effect on the liquid-phase chain oxidation of hydrocarbons. Peroxide radicals RO2 · do not add to N60 in hydrocarbons with active C—H bond, because the reaction is suppressed by the competing addition of RO2 · to the hydrocarbon. The addition of RO2 · radicals to N60 does occur in benzene (a solvent with strong C—H bonds) in the presence of low concentrations of the hydrocarbon oxidized. Fullerene N60 is found to exhibit a new type of liquid_phase CL, which is presumably generated upon thermal decomposition of fullerene peroxides formed by adding peroxy radicals to fullerene in the C60—AIBN—O2—C2H5Ph—PhH system. The CL spectrum exhibits long-wavelength maxima at 645 and 685 nm. The supposed CL emitters are keto derivatives of fullerene N60.

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Authors and Affiliations

  1. Institute of Petrochemistry and Catalysi, Russian Academy of Sciences, 141 prosp. Oktyabrya, 450075, Ufa, Russian Federation

    R. G. Bulgakov & Yu. G. Ponomareva

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  1. R. G. Bulgakov
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  2. Yu. G. Ponomareva
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Correspondence to R. G. Bulgakov.

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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 769-773, April, 2009.

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Bulgakov, R.G., Ponomareva, Y.G. Effect of the medium on the reactivity of fullerene N60 with respect to the peroxide radicals RO2 ·. Chemiluminescence in the C60—AIBN—O2—C2H5Ph—PhH system. Russ Chem Bull 58, 786–790 (2009). https://doi.org/10.1007/s11172-009-0095-2

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  • DOI: https://doi.org/10.1007/s11172-009-0095-2

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