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Conversion of isopropyl alcohol to acetone in fullerite cavities

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Abstract

Fullerite with cavities containing dichlorobenzene (DCB) and isopropyl alcohol (IPA) molecules was prepared by the addition of IPA to a solution of fullerene C60 in DCB. On heating in vacuo fullerite evolves IPA, and the temperature increase to 200—350 °C results in the evolution of acetone. No products of DCB conversion were observed. Possible products of the interaction of 60 with two IPA molecules were calculated by the quantum chemical method. New data on the fullerite structure were obtained by transmission electron microscopy X-ray powder diffractometry, mass spectrometry, IR spectroscopy, and other methods. One of the possible mechanisms of the reaction IPA → acetone was considered.

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References

  1. Yu. M. Shul’ga, V. M. Martynenko, A. F. Shestakov, S. A. Baskakov, S. V. Kulikov, V. N. Vasilets, T. L. Makarova, Yu. G. Morozov, Izv. Akad. Nauk, Ser. Khim., 2006, 662 [Russ. Chem. Bull., Int. Ed., 2006, 55, 687].

    Google Scholar 

  2. Yu. M. Shul’ga, V. M. Martynenko, S. A. Baskakov, A. M. Kolesnikova, Yu. V. Baskakova, G. A. Volkov, N. V. Chapysheva, V. F. Razumov, V. G. Sursaeva, Mass-spektrometriya [Mass Spectrometry], 2005, 2, 223 (in Russian).

    Google Scholar 

  3. B. D. Kruzhalov, B. I. Golovanenko, Sovmestnoe poluchenie fenola i atsetona [Combined Synthesis of Phenol and Acetone], Goskhimizdat, Moscow, 1963 (in Russian).

    Google Scholar 

  4. J. M. Tedder, A. Nechvatal, A. H. Jubb, Basic Organic Chemistry, John Wiley and Sons, London, 1975.

    Google Scholar 

  5. P. A. Heiney, G. B. M. Vaughan, J. E. Fischer, N. Cousel, D. E. Cox, J. R. D. Copley, D. A. Neumann, W. A. Kamita-kahara, K. M. Creegan, D. M. Cox, J. P. McCauley, Jr., A. B. Smith III, Phys. Rev., 1992, B45, 4544.

    Google Scholar 

  6. H. Werner, D. Bublak, U. Gobel, B. Henschke, W. Bensch, R. Schlogl, Angew. Chem., 1992, 104, 909.

    Article  CAS  Google Scholar 

  7. K. Prassides, Phys. Scr., 1993, 49, 735.

    Article  Google Scholar 

  8. R. Ceolin, J. L. Tamarit, D. O. Lopez, M. Barrio, V. Agafonov, H. Allouchi, F. Moussa, H. Szwarc, Chem. Phys. Lett., 1999, 314, 21.

    Article  CAS  Google Scholar 

  9. J. P. Perdew, K. Burke, M. Ernzerhof, Phys. Rev. Lett., 1996, 77, 3865.

    Article  CAS  Google Scholar 

  10. H. Basch, P. G. Jasien, Can. J. Chem., 1992, 70, 612.

    Google Scholar 

  11. D. N. Laikov, Chem. Phys. Lett., 1997, 281, 151.

    Article  CAS  Google Scholar 

  12. D. S. Bethune, G. Meijer, W. C. Tang, H. J. Rosen, W. G. Golden, H. Seki, C. A. Brown, M. S. deVries, Chem. Phys. Lett., 1991, 179, 181.

    Article  CAS  Google Scholar 

  13. X. D. Li, W. D. Cheng, D. S. Wu, H. Zhang, Y. J. Gong, Y. Z. Lan, Chem. Phys. Lett., 2003, 380, 480.

    Article  CAS  Google Scholar 

  14. T. S. Pokidova, N. T. Denisov, A. F. Shestakov, Neftekhimiya, 2008, 48, 174 [Petroleum Chem. (Engl. Transl.), 2008, 48]. Received September 27, 2007; in revised form May 6, 2008

    CAS  Google Scholar 

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Authors and Affiliations

  1. Institute of Problems of Chemical Physics, Russian Academy of Sciences, 1 prosp. Akad. Semenova, 142432, Chernogolovka, Moscow Region, Russian Federation

    Yu. M. Shul’ga, V. M. Martynenko, A. F. Shestakov, S. A. Baskakov, E. I. Knerel’man, A. N. Trukhanenok & G. I. Davydova

  2. Institute of Problems of Microelectronic Technology, Russian Academy of Sciences, 142432, Chernogolovka, Moscow Region, Russian Federation

    I. I. Khodos

  3. Department of Chemistry, Universitat Autonoma de Barcelona, 08193, Bellaterra (Cerdanyola del Valles), Barcelona, Spain

    D. N. Murav’ev

Authors
  1. Yu. M. Shul’ga
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  2. V. M. Martynenko
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  3. A. F. Shestakov
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  4. S. A. Baskakov
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  5. E. I. Knerel’man
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  6. A. N. Trukhanenok
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  7. G. I. Davydova
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  8. I. I. Khodos
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  9. D. N. Murav’ev
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Corresponding author

Correspondence to Yu. M. Shul’ga.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 742–748, April, 2009.

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Shul’ga, Y.M., Martynenko, V.M., Shestakov, A.F. et al. Conversion of isopropyl alcohol to acetone in fullerite cavities. Russ Chem Bull 58, 758–764 (2009). https://doi.org/10.1007/s11172-009-0091-6

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  • DOI: https://doi.org/10.1007/s11172-009-0091-6

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