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Interactions between nitrate ions and their effect on charge redistribution in pentaerythrityltetraammonium tetranitrate crystal

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Abstract

Based on a detailed study of the electron density distribution function in pentaerythrityltetraammonium tetranitrate, reconstructed from high resolution X-ray diffraction data, the effect of unusual (from the standpoint of electrostatic considerations) anion—anion contacts on the charge distribution in the crystal was analyzed. Interactions between the likely charged species can cause a significant redistribution of the charge density over the anionic (cationic) sublattice and, as a result, significantly affect the strength of conventional cation—anion bonds.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    Yu. V. Nelyubina, M. Yu. Antipin & K. A. Lyssenko

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  1. Yu. V. Nelyubina
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  2. M. Yu. Antipin
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  3. K. A. Lyssenko
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Correspondence to K. A. Lyssenko.

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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 735–741, April, 2009.

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Nelyubina, Y.V., Antipin, M.Y. & Lyssenko, K.A. Interactions between nitrate ions and their effect on charge redistribution in pentaerythrityltetraammonium tetranitrate crystal. Russ Chem Bull 58, 751–757 (2009). https://doi.org/10.1007/s11172-009-0090-7

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  • DOI: https://doi.org/10.1007/s11172-009-0090-7

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