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Coordination chemistry of anticrowns. Complexation of cyclic trimeric perfluoro-o-phenylenemercury (o-C6F4Hg)3 with the cyanoborohydride anion [H3BCN]− and triethylamineborane Et3NBH3

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Abstract

As was shown by IR spectroscopy, the reaction of the three-mercury anticrown (o-C6F4Hg)3 (1) with the [H3BCN]ion in THF affords the complexes {[(o-C6F4Hg)3][H3BCN](5) and [(o-C6F4Hg)3]2[H3BCN](6). Complex 6 was isolated from solution in the analytically pure state. According to X-ray diffraction data, complex 6 has a double-decker sandwich structure, in which the borohydride group of the [H3BCN]− anion is bound to one anticrown molecule by three B-H-Hg bridges, whereas the cyanide group is cooperatively coordinated by three mercury centers of another molecule 1 through the nitrogen atom. The reaction of compound 1 with triethylamineborane Et3NBH3 in THF affords the 1: 1 complex ∼[(o-C6F4Hg)3][Et3NBH3]∼ (7). In this adduct, the binding of the aminoborane to the mercury anticrown is also accomplished by B-H-Hg bridges. The stability constants of complexes 5 and 6 in THF were determined.

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References

  1. V. B. Shur, I. A. Tikhonova, in Encyclopedia of Supramolecular Chemistry, Eds J. L. Atwood, J. W. Steed, Marcel Dekker, Inc., New York, 2004, 68.

    Google Scholar 

  2. V. B. Shur, I. A. Tikhonova, Izv. Akad. Nauk, Ser. Khim., 2003, 2401 [Russ. Chem. Bull., Int. Ed., 2003, 52, 2539].

  3. T. J. Wedge, M. F. Hawthorne, Coord. Chem. Rev., 2003, 240, 111.

    CAS  Google Scholar 

  4. M. R. Haneline, R. E. Taylor, F. P. Gabba Chem. Eur. J., 2003, 21, 5188.

    Article  Google Scholar 

  5. J. J. Taylor, C. N. Burres, F. P. Gabba Organometallics, 2007, 26, 5252.

    Article  CAS  Google Scholar 

  6. J. D. Wuest, Acc. Chem. Res., 1999, 32, 81.

    Article  CAS  Google Scholar 

  7. I. A. Tikhonova, K. I. Tugashov, F. M. Dolgushin, P. V. Petrovskii, V. B. Shur, Organometallics, 2007, 26, 5193.

    Article  CAS  Google Scholar 

  8. I. A. Tikhonova, K. I. Tugashov, F. M. Dolgushin, A. A. Yakovenko, P. V. Petrovskii, G. G. Furin, A. P. Zaraisky, V. B. Shur, J. Organomet. Chem., 2007, 692, 953.

    Article  CAS  Google Scholar 

  9. P. Sartori, A. Golloch, Chem. Ber., 1968, 101, 2004.

    Article  CAS  Google Scholar 

  10. M. C. Ball, D. S. Brown, A. G. Massey, D. A. Wickens, J. Organomet. Chem., 1981, 206, 265.

    Article  CAS  Google Scholar 

  11. A. P. Zaraisky, O. I. Kachurin, L. I. Velichko, I. A. Tikhonova, G. G. Furin, V. B. Shur, J. Mol. Cat. A, 2005, 231, 103.

    Article  CAS  Google Scholar 

  12. I. A. Tikhonova, F. M. Dolgushin, A. A. Yakovenko, K. I. Tugashov, P. V. Petrovskii, G. G. Furin, V. B. Shur, Organometallics, 2005, 24, 3395.

    Article  CAS  Google Scholar 

  13. I. A. Tikhonova, A. A. Yakovenko, K. I. Tugashov, F. M. Dolgushin, V. V. Novikov, M. Yu. Antipin, V. B. Shur, Organometallics, 2006, 25, 6155.

    Article  CAS  Google Scholar 

  14. Z. Yan, I. A. Tikhonova, Z. Zhou, V. B. Shur, Y. Wu, Anal. Lett., 2005, 38, 377.

    CAS  Google Scholar 

  15. L. N. Saitkulova, E. V. Bakhmutova, E. S. Shubina, I. A. Tikhonova, G. G. Furin, V. I. Bakhmutov, N. P. Gambaryan, A. L. Chistyakov, I. V. Stankevich, V. B. Shur, L. M. Epstein, J. Organomet. Chem., 1999, 585, 201.

    Article  CAS  Google Scholar 

  16. K. Nakamoto, Infrared and Raman Spectra of Inorganic and Coordination Chemistry, 4th ed., John Wiley and Sons, Inc., 1986.

  17. O. A. Filippov, A. M. Filin, N. V. Belkova, V. N. Tsupreva, Y. V. Shmyrova, I. B. Sivaev, L. M. Epstein, E. S. Shubina, J. Mol. Struct., 2006, 790, 114.

    Article  CAS  Google Scholar 

  18. M. I. Bulatov, I. P. Kalinkin, Prakticheskoe rukovodstvo po fotokolorimetricheskim i spektrofotometricheskim metodam analiza [Manual on Photocolorimetric and Spectrophotometric Methods of Analysis], Khimiya, Moscow, 1968, p. 178 (in Russian).

  19. A. J. Canty, G. B. Deacon, Inorg. Chim. Acta, 1980, 45, L255.

    Article  Google Scholar 

  20. P. Pyykkö, M. Straka, Phys. Chem. Chem. Phys., 2000, 2, 2489.

    Article  Google Scholar 

  21. S. S. Batsanov, Zh. Neorg. Khim., 1991, 36, 3015 [Russ. J. Inorg. Chem., 1991, 36 (Engl. Transl.)].

    CAS  Google Scholar 

  22. I. A. Tikhonova, F. M. Dolgushin, A. I. Yanovsky, Z. A. Starikova, P. V. Petrovskii, G. G. Furin, V. B. Shur, J. Organomet. Chem., 2000, 613, 60.

    Article  CAS  Google Scholar 

  23. I. A. Tikhonova, F. M. Dolgushin, K. I. Tugashov, G. G. Furin, P. V. Petrovskii, V. B. Shur, Izv. Akad. Nauk, Ser. Khim., 2001, 1595 [Russ. Chem. Bull., Int. Ed., 2001, 50, 1673].

    Google Scholar 

  24. I. A. Tikhonova, F. M. Dolgushin, K. I. Tugashov, O. G. Ellert, V. M. Novotortsev, G. G. Furin, M. Yu. Antipin, V. B. Shur, J. Organomet. Chem., 2004, 689, 82.

    Article  CAS  Google Scholar 

  25. E. S. Shubina, I. A. Tikhonova, E. V. Bakhmutova, F. M. Dolgushin, M. Yu. Antipin, V. I. Bakhmutov, I. B. Sivaev, L. N. Teplitskaya, I. T. Chizhevsky, I. V. Pisareva, V. I. Bregadze, L. M. Epstein, V. B. Shur, Chem. Eur. J., 2001, 7, 3783.

    Article  CAS  Google Scholar 

  26. I. A. Tikhonova, E. S. Shubina, F. M. Dolgushin, K. I. Tugashov, L. N. Teplitskaya, A. M. Filin, I. B. Sivaev, P. V. Petrovskii, G. G. Furin, V. I. Bregadze, L. M. Epstein, V. B. Shur, Izv. Akad. Nauk, Ser. Khim., 2003, 570 [Russ. Chem. Bull., Int. Ed., 2003, 52, 594].

    Google Scholar 

  27. I. A. Tikhonova, F. M. Dolgushin, A. I. Yanovsky, Yu. T. Struchkov, A. N. Gavrilova, L. N. Saitkulova, E. S. Shubina, L. M. Epstein, G. G. Furin, V. B. Shur, J. Organomet. Chem., 1996, 508, 271.

    Article  CAS  Google Scholar 

  28. A. D. Becke, J. Chem. Phys., 1993, 98, 5648.

    Article  CAS  Google Scholar 

  29. P. J. Stephens, F. J. Devlin, C. F. Chabalowski, M. J. Frisch, J. Phys. Chem., 1994, 98, 11623.

    Article  CAS  Google Scholar 

  30. R. Boese, N. Niederprum, D. Blaser, in Molecules in Natural Science and Medicine, E. Horwood, New York, 1991, 103.

    Google Scholar 

  31. J. B. King, M. R. Haneline, M. Tsunoda, F. P. Gabba J. Am. Chem. Soc., 2002, 124, 9350.

    Article  CAS  Google Scholar 

  32. SMART V5.051 and SAINT V5.00, Area Detector Control and Integration Software, Bruker AXS Inc., Madison, WI-53719, USA, 1998.

  33. G. M. Sheldrick, SADABS, Bruker AXS Inc., Madison, WI-53719, USA, 1997.

    Google Scholar 

  34. G. M. Sheldrick, SHELXTL-97, Version 5.10, Bruker AXS Inc., Madison, WI-53719, USA, 1997.

    Google Scholar 

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    V. N. Tsupreva, O. A. Filippov, F. M. Dolgushin, K. I. Tugashov, A. I. Krylova, V. I. Bragin, I. A. Tikhonova, V. B. Shur, L. M. Epstein & E. S. Shubina

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  1. V. N. Tsupreva
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  2. O. A. Filippov
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  3. F. M. Dolgushin
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  4. K. I. Tugashov
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  5. A. I. Krylova
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  6. V. I. Bragin
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  7. I. A. Tikhonova
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  8. V. B. Shur
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Correspondence to V. B. Shur.

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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 12, pp. 2489–2496, December, 2008.

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Tsupreva, V.N., Filippov, O.A., Dolgushin, F.M. et al. Coordination chemistry of anticrowns. Complexation of cyclic trimeric perfluoro-o-phenylenemercury (o-C6F4Hg)3 with the cyanoborohydride anion [H3BCN]− and triethylamineborane Et3NBH3 . Russ Chem Bull 57, 2540–2547 (2008). https://doi.org/10.1007/s11172-008-0365-4

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  • DOI: https://doi.org/10.1007/s11172-008-0365-4

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