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2-(N-Alkylamino)-1-(trifluoroacetimidoyl)vinyl ketone derivatives as potential reagents in heterocyclic synthesis

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Abstract

A reaction of 3-acetyl-4-amino-5,5,5-trifluoropent-3-en-2-one diphenylboron chelate and ammonia or primary amines affords 4-amino- or 4-alkylamino-3-trifluoroacetimidoylpent-3-en-2-ones, new reagents which can be used for the synthesis of pyrimidines with trifluoromethyl group.

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Authors and Affiliations

  1. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation

    L. S. Vasil’ev, M. A. Prezent, A. V. Ignatenko & V. A. Dorokhov

Authors
  1. L. S. Vasil’ev
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  2. M. A. Prezent
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  3. A. V. Ignatenko
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  4. V. A. Dorokhov
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Corresponding author

Correspondence to V. A. Dorokhov.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp. 2313–2317, November, 2008.

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Vasil’ev, L.S., Prezent, M.A., Ignatenko, A.V. et al. 2-(N-Alkylamino)-1-(trifluoroacetimidoyl)vinyl ketone derivatives as potential reagents in heterocyclic synthesis. Russ Chem Bull 57, 2359–2363 (2008). https://doi.org/10.1007/s11172-008-0336-9

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  • DOI: https://doi.org/10.1007/s11172-008-0336-9

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