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Diastereomeric P*-mono- and P*,P*-bidentate diamidophosphite ligands based on 1,4:3,6-dianhydro-d-mannitol in asymmetric metallocomplex catalysis

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Abstract

Synthesis of diastereomeric mono- and bidentate diamidophosphites bearing P*-stereo-centers and phosphabicyclo[3.3.0]octane backbone and their coordination with rhodium(i) and palladium(ii) are considered. Their use in Rh-catalyzed asymmetric allylation allowed one to achieve 87% ee values and the use in Rh-catalyzed asymmetric hydrogenation gave up to 98% ee.

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Authors and Affiliations

  1. Department of Chemistry, S. A. Esenin Ryazan State University, 46 ul. Svobody, 390000, Ryazan, Russian Federation

    K. N. Gavrilov, S. V. Zheglov, P. A. Vologzhanin, E. A. Rastorguev, A. A. Shiryaev & M. G. Maksimova

  2. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    S. E. Lyubimov, E. B. Benetsky, A. S. Safronov, P. V. Petrovskii & V. A. Davankov

  3. Leibniz-Institut für Katalyse, Universität Rostock e.V., 29a A.-Einstein-Str., 18059, Rostock, Germany

    B. Schäffner & A. Börner

Authors
  1. K. N. Gavrilov
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  2. S. V. Zheglov
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  3. P. A. Vologzhanin
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  4. E. A. Rastorguev
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  5. A. A. Shiryaev
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  6. M. G. Maksimova
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  7. S. E. Lyubimov
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  8. E. B. Benetsky
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  9. A. S. Safronov
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  10. P. V. Petrovskii
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  11. V. A. Davankov
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  12. B. Schäffner
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  13. A. Börner
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Corresponding author

Correspondence to K. N. Gavrilov.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp. 2266–2274, November, 2008.

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Gavrilov, K.N., Zheglov, S.V., Vologzhanin, P.A. et al. Diastereomeric P*-mono- and P*,P*-bidentate diamidophosphite ligands based on 1,4:3,6-dianhydro-d-mannitol in asymmetric metallocomplex catalysis. Russ Chem Bull 57, 2311–2319 (2008). https://doi.org/10.1007/s11172-008-0327-x

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  • DOI: https://doi.org/10.1007/s11172-008-0327-x

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