Abstract
Carborane-containing phosphine ligands having different steric and electronic properties were synthesized. Testing of these ligands in the Pd-catalyzed Suzuki—Miyaura reaction showed higher catalytic activity for sterically congested phosphine ligands with acceptor carborane substituents.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
D. Alberico, M. E. Scott, M. Lautens, Chem. Rev., 2007, 107, 174.
Metal-Catalyzed Cross-coupling Reactions, Eds. F. Diederich, P. J. Stang, Wiley-VCH: Weinheim, Germany, 1998.
J. P. Corbet, G. Mignani, Chem. Rev., 2006, 106, 2651.
R. N. Grimes, Carboranes, New York, Academic Press, 1970.
V. I. Bregadze, Chem. Rev., 1992, 92, 209.
N. N. Godovikov, V. P. Balema, E. G. Rys, Usp. Khim., 1997, 66, 1125 [Russ. Chem. Rev., 1997, 66, 1017 (Engl. Transl.)].
L. I. Zakharkin, A. I. Kovredov, V. A. Ol’shevskaya, Izv. Akad. Nauk. Ser. Khim., 1981, 2159 [Russ. Chem. Bull., 1981, 30 (Engl. Transl.)].
L. I. Zakharkin, V. N. Kalinin, A. P. Snyakin, B. A. Kvasov, J. Organomet. Chem., 1969, 18, 19.
L. I. Zakharkin, G. G. Zhigareva, A. V. Kazantsev, Zh. Obshch. Khim., 1968, 38, 89 [J. Gen. Chem. USSR, 1968, 38 (Engl. Transl.)].
L. I. Zakharkin, M. N. Zhubekova, A. V. Kazantsev, Zh. Obshch. Khim., 1972, 42, 1024 [J. Gen. Chem. USSR, 1972, 42 (Engl. Transl.)].
S. E. Lyubimov, A. A. Tyutyunov, V. N. Kalinin, E. E. Said-Galiev, A. R. Khokhlov, P. V. Petrovskii, V. A. Davankov, Tetrahedron Lett., 2007, 48, 8217.
L. I. Zakharkin, A. I. Kovredov, V. A. Ol’shevskaya, Zh. Obshch. Khim., 1983, 53, 1431 [J. Gen. Chem. USSR, 1983, 53 (Engl. Transl.)].
L. I. Zakharkin, V. A. Ol’shevskaya, N. B. Boiko, Izv. Akad. Nauk. Ser. Khim., 1996, 719 [Russ. Chem. Bull., 1996, 45, 680 (Engl. Transl.)].
Author information
Authors and Affiliations
Corresponding author
Additional information
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp. 2262–2265, November, 2008.
Rights and permissions
About this article
Cite this article
Tyutyunov, A.A., Lyubimov, S.E., Rys, E.G. et al. Phosphorus derivatives of carboranes as ligands for Pd-catalyzed cross-coupling reactions. Russ Chem Bull 57, 2307–2310 (2008). https://doi.org/10.1007/s11172-008-0326-y
Received:
Revised:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11172-008-0326-y