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Cation mobility in systems based on high-molecular-weight sulfonic acids and polyaniline

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Abstract

Conduction properties and intermolecular interactions in systems based on high-molecular-weight sulfonic acids (poly(4-styrenesulfonic), poly(2-acrylamidomethylpropane-sulfonic), and perfluorosulfonic (MF-4SC)) and polyaniline were studied by impedance and IR spectroscopy. In all systems, an interpolyelectrolyte complex is formed due to strong hydrogen bonding. In two former cases, the interpolyelectrolyte complexes form nanodispersed powders with ionic and electronic conductivity. MF-4SC—polyaniline solutions were used for the membranes preparation with high ionic conductivity.

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Authors and Affiliations

  1. N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 119991, Moscow, Russian Federation

    I. A. Stenina, A. A. Il’ina, I. Yu. Pinus & A. B. Yaroslavtsev

  2. Department of Chemistry, M. V. Lomonosov Moscow State University, Building 3, 1 Leninskie Gory, 119992, Moscow, Russian Federation

    V. G. Sergeev

Authors
  1. I. A. Stenina
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  2. A. A. Il’ina
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  3. I. Yu. Pinus
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  4. V. G. Sergeev
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  5. A. B. Yaroslavtsev
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Corresponding author

Correspondence to A. B. Yaroslavtsev.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp. 2219–2222, November, 2008.

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Stenina, I.A., Il’ina, A.A., Pinus, I.Y. et al. Cation mobility in systems based on high-molecular-weight sulfonic acids and polyaniline. Russ Chem Bull 57, 2261–2264 (2008). https://doi.org/10.1007/s11172-008-0317-z

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  • DOI: https://doi.org/10.1007/s11172-008-0317-z

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