Abstract
Hitherto unknown phosphorus-containing 4,5-bis(diethoxyphosphorylmethyl)- and 4-methyl-5-diethoxyphosphorylmethylphthalonitriles were synthesized starting from o-xylene. Their tetramerization afforded free phthalocyanine ligands and their complexes with Zn, Ni, Co, and a number of rare-earth metals. The spectral and electrochemical properties of the phthalocyanines synthesized were studied.
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1634–1638, August, 2008.
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Ivanov, A.V., Kabanova, K.V., Breusova, M.O. et al. New phosphorus-containing metal phthalocyanine complexes. Synthesis and spectral and electrochemical studies. Russ Chem Bull 57, 1665–1670 (2008). https://doi.org/10.1007/s11172-008-0218-1
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DOI: https://doi.org/10.1007/s11172-008-0218-1