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Formation of stable carbonyl oxide by photooxidation of (phenyl)(2-thienyl)diazomethane

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Abstract

Formation of (phenyl)(2-thienyl)carbonyl oxide, which has the longest lifetime among known carbonyl oxides, has been registered by flash photolysis in acetonitrile at room temperature. It is consumed in the pseudomonomolecular reaction with the parent diazo compound.

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Correspondence to E. M. Chainikova.

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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 3, pp. 666–668, March, 2008.

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Mukhamadeeva, A.G., Chainikova, E.M. & Safiullin, R.L. Formation of stable carbonyl oxide by photooxidation of (phenyl)(2-thienyl)diazomethane. Russ Chem Bull 57, 679–681 (2008). https://doi.org/10.1007/s11172-008-0108-6

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  • DOI: https://doi.org/10.1007/s11172-008-0108-6

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