Abstract
Oxidative cyclocondensation of 4,4′-diamino-3,3′-bi-1,2,5-oxadiazole and isomeric 3(4)-amino-4(3)-(4-amino-1,2,5-oxadiazol-3-yl)-1,2,5-oxadiazole 2-oxides under the action of dibro-moisocyanurate gave 12- and 18-membered macrocyclic systems containing two or three bifurazanyl or furazanylfuroxanyl moieties linked by azo bridges. The latter were oxidized into azoxy groups with Caro’s acid in 20% oleum.
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 3, pp. 631–638, March, 2008.
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Epishina, M.A., Kulikov, A.S. & Makhova, N.N. Synthesis of macrocyclic systems from 4,4′-diamino-3,3′-bi-1,2,5-oxadiazole and 3(4)-amino-4(3)-(4-amino-1,2,5-oxadiazol-3-yl)-1,2,5-oxadiazole 2-oxides. Russ Chem Bull 57, 644–651 (2008). https://doi.org/10.1007/s11172-008-0101-0
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DOI: https://doi.org/10.1007/s11172-008-0101-0