Skip to main content
SpringerLink
Log in

Synthesis, structure, and properties of the [RuNO(NH3)5][Co(CN)6] complex containing a photochromic cation

  • Full Articles
  • Published:
Russian Chemical Bulletin Aims and scope

Abstract

The salt of cobalt hexacyanide with the photochromic mononitrosyl cation [RuNO(NH3)5]3+ with the composition [RuNO(NH3)5][Co(CN)6] was synthesized. Single crystals of the salt were grown, and the crystal structure was solved. The photochromic properties were studied by differential scanning calorimetry (DSC).

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. O. Sato, T. Iyoda, A. Fujishimi, K. Hashimoto, Science, 1996, 272, 704.

    Article  CAS  Google Scholar 

  2. P. Gütlich, Y. Garcia, T. Woike, Coord. Chem. Rev., 2001, 219–221, 839–879.

    Article  Google Scholar 

  3. M. L. Boillot, C. Roux, J.-P. Audière, A. Dausse, J. Zarembowitch, Inorg. Chem., 1996, 35, 3975.

    Article  CAS  Google Scholar 

  4. S. Decurtins, P. Gütlich, C. P. Köhler, H. Spiering, A. Hauser, Z. Phys. Chem., 1984, 105, 1.

    CAS  Google Scholar 

  5. Z.-Z. Gu, O. Sato, T. Iyoda, K. Hashimoto, A. Fujishima, J. Phys. Chem., 1996, 100, 18289

    Google Scholar 

  6. Z.-Z. Gu, O. Sato, T. Iyoda, K. Hashimoto, A. Fujishima, Mol. Cryst. Liq. Cryst., 1996; 286, 147

    Article  Google Scholar 

  7. Z.-Z. Gu, O. Sato, T. Iyoda, K. Hashimoto, A. Fujishima, Chem. Mater., 1997, 9, 1092.

    Article  CAS  Google Scholar 

  8. P. Coppens, D. F. Fomichev, M. D. Carducci, K. Culp, J. Chem. Soc., Dalton Trans., 1998, 865.

  9. P. Coppens, I. Novozhilova, A. Kovalevsky, Chem. Rev., 2002, 102,4, 861.

    Article  CAS  Google Scholar 

  10. D. Schaniel, T. Woike, C. Boskovic, H.-U. Güdel, Chem. Phys. Lett., 2004, 390, 347.

    Article  CAS  Google Scholar 

  11. Y. Morioka, A. Ishikawa, H. Tomizava, E. Miki, J. Chem.Soc., Dalton Trans., 2000, 781.

  12. M. Kawano, A. Ishikawa, Y. Morioka, H. Tomizawa, E. Miki, Y. Ohashi, J. Chem Soc., Dalton Trans., 2000, 2425.

  13. D. Schaniel, T. Woike, B. Delley, C. Boskovich, D. Biner, K. W. Kramer, H.-U. Güdel, Phys. Chem. Chem. Phys., 2005, 7, 1164.

    Article  CAS  Google Scholar 

  14. L. A. Kushch, L. S. Plotnikova, Yu. N. Shvachko, V. A. Emel’yanov, E. B. Yagubskii, G.V. Shilov, S. M. Aldoshin, J. Phys. IV France, 2004, 114, 459.

    Article  CAS  Google Scholar 

  15. L. A. Kushch, L. S. Kurochkina, E. B. Yagubskii, G. V. Shilov, S. M. Aldoshin, V. A. Emel’yanov, Y. N. Shvachko, V. S. Mironov, D. Schaniel, T. Woike, C. Carbonera, C. Mathoniére, Eur. J. Inorg. Chem., 2006, 4074.

  16. L. Kushch, E. Yagubskii, M. Il’in, D. Schaniel, Th. Woike, S. Golhen, O. Cador, L. Ouahab, J. Cluster Sci., 2006, 17, 303.

    Article  CAS  Google Scholar 

  17. I. Lewis, R. J. Irving, G. Wilkinson, J. Inorg. Nuclear Chem., 1958, 7, 32.

    Article  CAS  Google Scholar 

  18. S. Ferlay, H. W. Schmalle, G. Francese, H. Stoeckli-Evans, M. Imlau, D. Schaniel, T. Woike, Inorg. Chem., 2004, 43, 3500.

    Article  CAS  Google Scholar 

  19. G. M. Sheldick, SHELXL97, Program for Crystal Structure Refinement, University of Gottingen, Germany, 1997.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Problems of Chemical Physics, Russian Academy of Sciences, 1 prosp. Akad. Semenova, 142432, Chernogolovka, Moscow Region, Russian Federation

    L. A. Kushch, G. V. Shilov & E. B. Yagubskii

  2. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3 prosp. Akad. Lavrentieva, 630090, Novosibirsk, Russian Federation

    M. A. Il’in

  3. Physical Institute, University of Cologne, Zulpicher Str. 77, D-50937, Cologne, Germany

    T. Woike & D. Schaniel

Authors
  1. L. A. Kushch
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. G. V. Shilov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. M. A. Il’in
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. T. Woike
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. D. Schaniel
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. E. B. Yagubskii
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to L. A. Kushch.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 3, pp. 545–548, March, 2008.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Kushch, L.A., Shilov, G.V., Il’in, M.A. et al. Synthesis, structure, and properties of the [RuNO(NH3)5][Co(CN)6] complex containing a photochromic cation. Russ Chem Bull 57, 557–560 (2008). https://doi.org/10.1007/s11172-008-0086-8

Download citation

  • Received:

  • Revised:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11172-008-0086-8

Key words

Search

Navigation