Abstract
The new scandium rhodium boride Sc4Rh17B12 was synthesized by arc-melting of the elements followed by annealing in inert atmosphere. The crystal structure of Sc4Rh17B12 was solved using single crystal X-ray diffraction data. The structure can be described as a three-dimensional frame-work formed by trigonal prisms [BRh6] and [BRh5Sc] with isolated boron atoms inside the prisms and trigonal prisms [BRh5B] representing the coordination polyhedra of paired boron atoms. The temperature dependences of the magnetic susceptibility and specific resistance of Sc4Rh17B12 revealed that the compound is a Pauli paramagnet and shows metal-like specific resistance.
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Max-Planck-Institut für Chemische Physik fester Stoffe, 40 Nöthnitzer Straße, 01187 Dresden, Deutschland.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 3, pp. 521–529, March, 2008.
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Alekseeva, A.M., Leithe-Jasper, A., Prots, Y. et al. New scandium rhodium boride Sc4Rh17B12 with a framework structure: synthesis, crystal structure, and properties. Russ Chem Bull 57, 532–540 (2008). https://doi.org/10.1007/s11172-008-0082-z
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DOI: https://doi.org/10.1007/s11172-008-0082-z