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Carboranylphosphites as new ligands for Rh-catalyzed asymmetric hydrogenation

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Abstract

First representatives of chiral carborane-based phosphite ligands were synthesized. The enantiomeric excess in the Rh-catalyzed hydrogenation of dimethyl itaconate with the use of these ligands reaches 67% in CH2Cl2 and 62% in supercritical CO2, the ee and conversion being strongly dependent on the hydrogen pressure.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    S. E. Lyubimov, A. S. Safronov, A. A. Tyutyunov, V. N. Kalinin, E. E. Said-Galiev, A. R. Khokhlov, P. V. Petrovskii, P. M. Valetskii & V. A. Davankov

Authors
  1. S. E. Lyubimov
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  2. A. S. Safronov
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  3. A. A. Tyutyunov
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  4. V. N. Kalinin
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  5. E. E. Said-Galiev
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  6. A. R. Khokhlov
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  7. P. V. Petrovskii
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  8. P. M. Valetskii
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  9. V. A. Davankov
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Corresponding author

Correspondence to S. E. Lyubimov.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 337–340, February, 2008.

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Lyubimov, S.E., Safronov, A.S., Tyutyunov, A.A. et al. Carboranylphosphites as new ligands for Rh-catalyzed asymmetric hydrogenation. Russ Chem Bull 57, 345–348 (2008). https://doi.org/10.1007/s11172-008-0053-4

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  • DOI: https://doi.org/10.1007/s11172-008-0053-4

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