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Oxidation of fullerene C60 with the system aluminum tri-tert-butoxide—tert-butyl hydroperoxide

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Abstract

Oxidation of fullerene C60 with the system aluminum tri-tert-butoxide-tert-butyl hydroperoxide, in which electron-excited dioxygen is generated, gave a complex mixture of fullerene oxides C60O x (x = 1–6). The pathways of their formation were proposed.

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Authors and Affiliations

  1. N. I. Lobachevsky Nizhny Novgorod State University, 23 prosp. Gagarina, 603950, Nizhny Novgorod, Russian Federation

    E. A. Zaburdaeva & V. A. Dodonov

  2. G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, 49 ul. Tropinina, 603600, Nizhny Novgorod, Russian Federation

    M. A. Lopatin & T. I. Lopatina

Authors
  1. E. A. Zaburdaeva
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  2. M. A. Lopatin
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  3. T. I. Lopatina
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  4. V. A. Dodonov
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Corresponding author

Correspondence to E. A. Zaburdaeva.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 296–300, February, 2008.

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Zaburdaeva, E.A., Lopatin, M.A., Lopatina, T.I. et al. Oxidation of fullerene C60 with the system aluminum tri-tert-butoxide—tert-butyl hydroperoxide. Russ Chem Bull 57, 304–308 (2008). https://doi.org/10.1007/s11172-008-0047-2

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  • DOI: https://doi.org/10.1007/s11172-008-0047-2

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