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Benzene complex [(η-9-SMe2-7,8-C2B9H10)Fe(η-C6H6)]+ as a synthon for the cationic ferracarborane moiety

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Abstract

The photochemical reaction of [(η5-C6H7)Fe(η-C6H6)]+ (1) with the [(η-9-SMe2-7,8-C2B9H10)]− anion followed by the treatment of the resulting ferracarborane (η-9-SMe2-7,8-C2B9H10)Fe(η5-C6H7) (2) with hydrochloric acid afforded the benzene complex [(η-9-SMe2-7,8-C2B9H10)Fe(η-C6H6)]+ (3). The reaction of cation 3 with ButNC produced the isonitrile complex [(η-9-SMe2-7,8-C2B9H10)Fe(tBuNC)3]+ (4). The structure of the complex [4]PF6 was established by X-ray diffraction.

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References

  1. T. P. Gill and K. R. Mann, Inorg. Chem., 1980, 19, 3007.

    Article  CAS  Google Scholar 

  2. A. R. Kudinov, M. I. Rybinskaya, Yu. T. Struchkov, A. I. Yanovskii, and P. V. Petrovskii, J. Organomet. Chem., 1987, 336, 187.

    Article  CAS  Google Scholar 

  3. O. J. Scherer, T. Brück, and G. Wolmershäuser, Chem. Ber., 1989, 122, 2049.

    Article  CAS  Google Scholar 

  4. A. R. Kudinov, D. V. Muratov, M. I. Rybinskaya, P. V. Petrovskii, A. V. Mironov, T. V. Timofeeva, Yu. L. Slovokhotov, and Yu. T. Struchkov, J. Organomet. Chem., 1991, 414, 97.

    Article  CAS  Google Scholar 

  5. A. R. Kudinov, D. A. Loginov, Z. A. Starikova, P. V. Petrovskii, M. Corsini, and P. Zanello, Eur. J. Inorg. Chem., 2002, 3018.

  6. C. A. Turner, W. Ding, I. J. Amster, and C. Kutal, Coord. Chem. Rev., 2002, 229, 9.

    Article  CAS  Google Scholar 

  7. V. Beck and D. O’Hare, J. Organomet. Chem., 2004, 689, 3920.

    Article  CAS  Google Scholar 

  8. R. H. Herber, A. R. Kudinov, P. Zanello, I. Nowik, D. S. Perekalin, V. I. Meshcheryakov, K. A. Lyssenko, M. Corsini, and S. Fedi, Eur. J. Inorg. Chem., 2006, 1786.

  9. R. N. Grimes, in Comprehensive Organometallic Chemistry II, vol. 1, Eds E. W. Abel, F. G. A. Stone, and G. Wilkinson, Pergamon Press, New York, 1995, p. 373.

    Google Scholar 

  10. A. R. Kudinov, R. T. Bogoudinov, P. V. Petrovskii, and M. I. Rybinskaya, Izv. Akad. Nauk, Ser. Khim., 1999, 592 [Russ. Chem. Bull., 1999, 48, 586 (Engl. Transl.)].

    Google Scholar 

  11. D. A. Loginov, D. V. Muratov, Z. A. Starikova, P. V. Petrovskii, and A. R. Kudinov, J. Organomet. Chem., 2006, 691, 3646.

    Article  CAS  Google Scholar 

  12. M. Corsini, S. Losi, E. Grigiotti, F. Rossi, P. Zanello, A. R. Kudinov, D. A. Loginov, M. M. Vinogradov, and Z. A. Starikova, J. Solid State Electrochem., 2007, 11, 1643.

    Article  CAS  Google Scholar 

  13. D. A. Loginov, M. M. Vinogradov, Z. A. Starikova, P. V. Petrovskii, and A. R. Kudinov, Izv. Akad. Nauk, Ser. Khim., 2007, 2088 [Russ. Chem. Bull., Int. Ed., 2007, 56, No. 11].

    Google Scholar 

  14. Y.-K. Yan, D. M. P. Mingos, T. E. Müller, D. J. Williams, and M. Kurmoo, J. Chem. Soc., Dalton Trans., 1994, 1735.

  15. Y.-K. Yan, D. M. P. Mingos, and D. J. Williams, J. Organomet. Chem., 1995, 498, 267.

    Article  CAS  Google Scholar 

  16. V. I. Meshcheryakov, P. S. Kitaev, K. A. Lyssenko, Z. A. Starikova, P. V. Petrovskii, Z. Janoušek, M. Corsini, F. Laschi, P. Zanello, and A. R. Kudinov, J. Organomet. Chem., 2005, 690, 4745.

    Article  CAS  Google Scholar 

  17. APEX2 Softwarwe Package, Bruker AXS Inc., 5465, East Cheryl Parkway, Madison, Wisconsin, USA, 2005.

  18. SHELXTL v. 5.10, Structure Determination Software Suite, Bruker AXS, Madison, Wisconsin, USA, 1998.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    D. A. Loginov, M. M. Vinogradov, L. S. Shul’pina, A. V. Vologzhanina, P. V. Petrovskii & A. R. Kudinov

Authors
  1. D. A. Loginov
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  2. M. M. Vinogradov
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  3. L. S. Shul’pina
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  4. A. V. Vologzhanina
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  5. P. V. Petrovskii
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  6. A. R. Kudinov
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Corresponding author

Correspondence to A. R. Kudinov.

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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 2046–2048, October, 2007.

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Loginov, D.A., Vinogradov, M.M., Shul’pina, L.S. et al. Benzene complex [(η-9-SMe2-7,8-C2B9H10)Fe(η-C6H6)]+ as a synthon for the cationic ferracarborane moiety. Russ Chem Bull 56, 2118–2120 (2007). https://doi.org/10.1007/s11172-007-0331-6

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  • DOI: https://doi.org/10.1007/s11172-007-0331-6

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