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P-Chiral monodentate diamidophosphites as ligands for Rh-catalyzed asymmetric reactions

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Abstract

A series of P-chiral monodentate diamidophosphite ligands of the 1,3-diaza-2-phosphabicyclo[3.3.0]octane family was tested in the Rh-catalyzed hydrogenation of dimethyl itaconate and addition of phenylboronic acid at the carbonyl group of trans-cinnamaldehyde. The enantioselectivities and conversions of these reactions are strongly dependent on the nature of the exo-cyclic substituent of the ligand.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    S. E. Lyubimov, V. A. Davankov, P. V. Petrovskii & N. M. Loim

Authors
  1. S. E. Lyubimov
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  2. V. A. Davankov
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  3. P. V. Petrovskii
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  4. N. M. Loim
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Corresponding author

Correspondence to S. E. Lyubimov.

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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 2023–2025, October, 2007.

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Lyubimov, S.E., Davankov, V.A., Petrovskii, P.V. et al. P-Chiral monodentate diamidophosphites as ligands for Rh-catalyzed asymmetric reactions. Russ Chem Bull 56, 2094–2096 (2007). https://doi.org/10.1007/s11172-007-0326-3

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  • DOI: https://doi.org/10.1007/s11172-007-0326-3

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