Abstract
The kinetics was studied for the reactions of ozone with model lignin compounds, viz., phenol, veratrole, veratric aldehyde, and veratric alcohol. Using the mass transfer model for a chemical reaction based on the film theory, the reaction rate constants were calculated. The reaction rate constants determined by both the ozone absorption rate and changes in the substrate concentration coincide satisfactorily, indicating adequacy of the kinetic model chosen. A relationship between the structure of the compounds under study and their reactivity was found.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
K. V. Sarkanen and I. Lyudvig, Ligniny — struktura, sostav i reaktsii [Lignins: Structure, Composition, and Reactions], Lesnaya Promyshlennost’, Moscow, 1975, 613 pp. (in Russian).
P. S. Bailey, Ozonization in Organic Chemistry, Academic Press, New York, 1982, Vol. 2, 31 p.
P. V. Danckwerts, Gas-Liquid Reactions, McGrow-Hill Book Company, New York, 1970, 256 pp.
H. Benbelkacem and H. Debellefontaine, Chem. Eng. Proc., 2003, 42, 723.
M. M. Ksenofontova, A. N. Mitrofanova, E. A. Tveritinova, A. N. Pryakhin, and V. V. Lunin, Zh. Fiz. Khim., 2003, 77, 1028 [Russ. J. Phys. Chem., 2003, 77, No. 6 (Engl. Transl.)].
A. D. Mitrofanov, Deposited with ONIITEKhIM, Cherkassy, 1979, Ferbuary 5, No. 2363-79 (in Russian).
V. N. Sokolov and I. V. Domanskii, Gazozhidkostnye reaktory [Gas-Liquid Reactors], Mashinostroenie, Leningrad, 1976, 216 pp. (in Russian).
V. A. Yakobi, Zh. Fiz. Khim., 1992, 66, 867 [Russ. J. Phys. Chem., 1992, 66, No. 4 (Engl. Transl.)].
G. A. Galstyan, N. F. Tyupalo, and S. D. Razumovskii, Ozon i ego reaktsii s aromaticheskimi soedineniyami v zhidkoi faze [Ozone and Its Reactions with Aromatic Compounds in the Liquid Phase], Eastern-Ukrainian National University, Lugansk, 2003, 298 (in Russian).
W. J. Masschelein, Ozone Science Eng., 1998, 20, 491.
F. J. Beltran, J. F. Garcia-Araya, and J. M. Encinar, Ozone Science Eng., 1997, 19, 281.
H. Benbelkacem, H. Cano, S. Mathe, and H. Debellefontaine, Ozone Science Eng., 2003, 25, 18.
R. C. Reid, J. M. Prausnitz, and T. K. Sherwood, The Properties of Gases and Liquids, McGraw-Hill Book Gompany, New York, 1987, 741 pp.
J. Beltran-Heredia and J. Torregrosa, Wat. Res., 2001, 35, 1077.
J. Hoigne and H. Bader, Wat. Res., 1983, 17, 185.
P. C. Singer and M. D. Gurol, Wat. Res., 1983, 17, 1163.
Author information
Authors and Affiliations
Corresponding author
Additional information
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 1941–1946, October, 2007.
Rights and permissions
About this article
Cite this article
Khudoshin, A.G., Mitrofanova, A.N. & Lunin, V.V. Kinetics of gas-liquid ozonization of veratrole and its derivatives. Russ Chem Bull 56, 2008–2013 (2007). https://doi.org/10.1007/s11172-007-0313-8
Received:
Revised:
Issue Date:
DOI: https://doi.org/10.1007/s11172-007-0313-8