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Chemiluminescence in the reaction of LnI2 (Ln = Dy, Nd) with water

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Abstract

Chemiluminescence (CL) upon the reaction of crystalline LnI2 (Ln = Dy, Nd) with water was found. The CL emitters are the Ln3+* electron-excited ions (Dy3+*, λmax = 470, 570 nm; Nd3+*, λ = 700–1200 nm) generated by the electron transfer from the LnII ions to the H2O molecules. The identified reaction products are H2, dissolved LnI3, and insoluble LnI(OH)2 (49–51% and 48–50% yield for DyI2 and NdI2, respectively). The treatment of NdI2 with an H2O solution in THF gives the NdI2OH(thf)2·3H2O complex and hydrogen.

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Authors and Affiliations

  1. Institute of Petroleum Chemistry and Catalysis, Russian Academy of Sciences, 141 prosp. Oktyabrya, 450075, Ufa, Russian Federation

    R. G. Bulgakov, S. P. Kuleshov, Z. S. Kinzyabaeva & I. R. Masalimov

  2. G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, 49 ul. Tropinina, 603950, Nizhnii Novgorod, Russian Federation

    A. A. Fagin & M. N. Bochkarev

Authors
  1. R. G. Bulgakov
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  2. S. P. Kuleshov
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  3. Z. S. Kinzyabaeva
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  4. A. A. Fagin
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  5. I. R. Masalimov
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  6. M. N. Bochkarev
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Correspondence to R. G. Bulgakov.

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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 1890–1893, October, 2007.

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Bulgakov, R.G., Kuleshov, S.P., Kinzyabaeva, Z.S. et al. Chemiluminescence in the reaction of LnI2 (Ln = Dy, Nd) with water. Russ Chem Bull 56, 1956–1959 (2007). https://doi.org/10.1007/s11172-007-0304-9

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  • DOI: https://doi.org/10.1007/s11172-007-0304-9

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