Skip to main content
SpringerLink
Log in

Synthesis and some properties of neodymium(III) and dysprosium(III) iodide hydrides LnI2H

  • Published:
Russian Chemical Bulletin Aims and scope

Abstract

The iodide hydrides NdI2H (1) and DyI2H (2) were obtained by the reactions of diiodides NdI2 (3) and DyI2 (4) with hydrogen at atmospheric pressure and temperature of 120–200 °C. Hydrolysis of products 1 and 2 gives hydrogen in a high yield. The reactions of 1 with phenol and of 2 with isopropyl alcohol in THF afford the iodide phenoxide NdI2(OPh)(THF)4 and iodide isopropoxide DyI2(OPri)(PriOH)3, respectively. The reaction of 2 with cyclopentadiene is accompanied by disproportionation and gives, besides dihydrogen, Cp2DyI(THF)2 and DyI3(THF)3.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. M. N. Bochkarev, Coord. Chem. Rev., 2004, 248, 835.

    Article  CAS  Google Scholar 

  2. M. E. Kost, A. L. Shilov, V. I. Mikheeva, S. I. Uspenskaya, V. I. Novokshonov, K. E. Mironov, M. N. Abdusalyamova, A. A. Eliseev, G. M. Kuz’micheva, and G. B. Seifer, Soedineniya redkozemel’nykh elementov. Gidridy, boridy, karbidy, fosfidy, pniktidy, khal’kogenidy, psevdogalogenidy [Rare Earth Element Compounds. Hydrides, Borides, Carbides, Phosphides, Pnictides, Chalcogenides, Pseudohalides] Nauka, Moscow, 1983, 272 pp. (in Russian).

    Google Scholar 

  3. M. Ephritikhine, Chem. Rev., 1997, 97, 2193.

    Article  CAS  Google Scholar 

  4. N. B. Mikheev, Zh. Neorg. Khim., 1984, 29, 450 [J. Inorg. Chem. USSR, 1984, 29 (Engl. Transl.)].

    CAS  Google Scholar 

  5. M. N. Bochkarev, E. A. Fedorova, O. A. Vasina, I. M. Penyagina, S. Ya. Khorshev, and A. V. Protchenko, Metalloorgan. Khim., 1989, 2, 703 [Organomet. Chem. USSR, 1989, 2, 363].

    CAS  Google Scholar 

  6. E. A. Fedorova, A. A. Trifonov, E. N. Kirillov, and M. N. Bochkarev, Izv. Akad. Nauk. Ser. Khim., 2000, 947 [Russ. Chem. Bull., Int. Ed., 2000, 49, 946].

    Google Scholar 

  7. M. N. Bochkarev, L. N. Zakharov, and G. S. Kalinina, Organoderivatives of Rare Earth Elements, Kluwer Academic Publishers, Dordrecht, 1995, 532 p.

    Google Scholar 

  8. M. N. Bochkarev and A. A. Fagin, Chem. Eur. J., 1999, 5, 2990.

    Article  CAS  Google Scholar 

  9. W. J. Evans and M. A. Horzbor, J. Organomet. Chem., 1987, 326, 299.

    Article  CAS  Google Scholar 

  10. G. V. Khoroshen’kov, A. A. Fagin, M. N. Bochkarev, S. Dehert, and G. Schuman, Izv. Akad. Nauk. Ser. Khim., 2003, 1627 [Russ. Chem. Bull., Int. Ed., 2003, 52, 1715].

    Google Scholar 

  11. M. A. Katkova, G. K. Fukin, A. A. Fagin, and M. N. Bochkarev, J. Organomet. Chem., 2003, 682, 218.

    Article  CAS  Google Scholar 

  12. A. A. Protchenko and M. N. Bochkarev, Pribory i tekhnika eksperimenta [Experimental Instruments and Techniques], Nauka, Moscow, 1990, 1, 194 pp. (in Russian).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. G. A. Razuvaev Institute of Organometallic Chemistry of the Russian Academy of Sciences, 49 ul. Tropinina, 603950, Nizhnii Novgorod, Russian Federation

    M. N. Bochkarev, A. A. Logunov & M. E. Burin

Authors
  1. M. N. Bochkarev
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. A. Logunov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. M. E. Burin
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to M. N. Bochkarev.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 1887–1889, October, 2007.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Bochkarev, M.N., Logunov, A.A. & Burin, M.E. Synthesis and some properties of neodymium(III) and dysprosium(III) iodide hydrides LnI2H. Russ Chem Bull 56, 1953–1955 (2007). https://doi.org/10.1007/s11172-007-0303-x

Download citation

  • Received:

  • Revised:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11172-007-0303-x

Key words

Search

Navigation