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Solvent-free oxidation of aliphatic alcohols with ceric ammonium nitrate—lithium bromide system

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Abstract

Esters are formed during the solvent-free oxidation of primary aliphatic C5–C9 alcohols with Ce(NH4)2(NO3)6–LiBr, whereas secondary octan-2-ol gives a mixture of isomeric 1-and 3-bromooctan-2-ones.

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Authors and Affiliations

  1. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation

    N. I. Kapustina, L. L. Sokova & G. I. Nikishin

  2. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    R. G. Gasanov

Authors
  1. N. I. Kapustina
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  2. L. L. Sokova
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  3. R. G. Gasanov
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  4. G. I. Nikishin
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Correspondence to N. I. Kapustina.

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Dedicated to Academician V. A. Tartakovsky in honor of his 75th anniversary.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1445—1450, August, 2007.

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Kapustina, N.I., Sokova, L.L., Gasanov, R.G. et al. Solvent-free oxidation of aliphatic alcohols with ceric ammonium nitrate—lithium bromide system. Russ Chem Bull 56, 1501–1506 (2007). https://doi.org/10.1007/s11172-007-0232-8

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  • DOI: https://doi.org/10.1007/s11172-007-0232-8

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