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Chemical modification of usnic acid 1. Reaction of (+)-usnic acid with perfluoroolefins

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Abstract

The reactions of the natural lichen metabolite, (+)-usnic acid, with a series of commercially available polyfluoroolefins (tetrafluoroethylene, chlorotrifluoroethylene, hexafluoropropene, perfluoro-2-methylpent-2-ene, and 1,2-dichlorooctafluorocyclohex-1-ene) afford its 7-O-polyfluoroalkyl and perfluorovinyl ethers.

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Authors and Affiliations

  1. N. N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, 9 prosp. Akad. Lavrent’eva, 630090, Novosibirsk, Russian Federation

    G. G. Furin, O. A. Luzina, M. P. Polovinka, N. F. Salakhutdinov & G. A. Tolstikov

  2. Novosibirsk State University, 2 ul. Pirogova, 630090, Novosibirsk, Russian Federation

    R. I. Sokuev & M. P. Polovinka

Authors
  1. G. G. Furin
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  2. O. A. Luzina
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  3. R. I. Sokuev
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  4. M. P. Polovinka
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  5. N. F. Salakhutdinov
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  6. G. A. Tolstikov
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Corresponding author

Correspondence to N. F. Salakhutdinov.

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Dedicated to the memory of Academician N. N. Vorozhtsov on the 100th anniversary of his birth.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 1198–1202, June, 2007.

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Furin, G.G., Luzina, O.A., Sokuev, R.I. et al. Chemical modification of usnic acid 1. Reaction of (+)-usnic acid with perfluoroolefins. Russ Chem Bull 56, 1244–1248 (2007). https://doi.org/10.1007/s11172-007-0188-8

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  • DOI: https://doi.org/10.1007/s11172-007-0188-8

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