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Microstructure of 1,2-trans-and 1,4-trans-poly(penta-1,3-dienes)

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Abstract

Microstructures of 1,2-trans-and 1,4-trans-poly(penta-1,3-dienes) synthesized using different catalysts were determined by high resolution 13C NMR spectroscopy. The content of dyad combinations of the 1,4-and 1,2-structures was quantitatively determined in hydrogenated poly(penta-1,3-dienes) from the ratio of intensities of the characteristic signals of the carbon atoms of the methylene groups in the 13C NMR spectra.

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Authors and Affiliations

  1. Volga Basin Ecology Institute, Russian Academy of Sciences, 10 ul. Komzina, 445003, Tol’yatti, Russian Federation

    V. A. Rozentsvet

  2. S. V. Lebedev Research Institute of Synthetic Rubber, 1 Gapsal’skaya ul., 198035, St. Petersburg, Russian Federaion

    A. S. Khachaturov & V. P. Ivanova

Authors
  1. V. A. Rozentsvet
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  2. A. S. Khachaturov
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  3. V. P. Ivanova
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Correspondence to V. A. Rozentsvet.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 1113–1118, June, 2007.

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Rozentsvet, V.A., Khachaturov, A.S. & Ivanova, V.P. Microstructure of 1,2-trans-and 1,4-trans-poly(penta-1,3-dienes). Russ Chem Bull 56, 1156–1161 (2007). https://doi.org/10.1007/s11172-007-0175-0

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  • DOI: https://doi.org/10.1007/s11172-007-0175-0

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