Abstract
Reaction of resorcinol with phosphorylated acetals or ethoxyvinylphosphonic acid esters in acidic media leads to calix[4]resorcinarenes, containing dialkoxyphosphoryl fragments at the lower rim of the molecule. When the alkyl substituent in alkoxy groups at phosphorus atom is not very long, a partial hydrolysis of the initially formed products takes place to give calixarenes with alkoxyhydroxyphosphoryl fragments.
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 1102–1106, June, 2007.
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Burilov, A.R., Knyazeva, I.R., Sadykova, Y.M. et al. Synthesis of calix[4]resorcinarenes, containing phosphoryl fragments at the lower rim of the molecule. Russ Chem Bull 56, 1144–1148 (2007). https://doi.org/10.1007/s11172-007-0173-2
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DOI: https://doi.org/10.1007/s11172-007-0173-2