Skip to main content
Log in

Synthesis of calix[4]resorcinarenes, containing phosphoryl fragments at the lower rim of the molecule

  • Published:
Russian Chemical Bulletin Aims and scope

Abstract

Reaction of resorcinol with phosphorylated acetals or ethoxyvinylphosphonic acid esters in acidic media leads to calix[4]resorcinarenes, containing dialkoxyphosphoryl fragments at the lower rim of the molecule. When the alkyl substituent in alkoxy groups at phosphorus atom is not very long, a partial hydrolysis of the initially formed products takes place to give calixarenes with alkoxyhydroxyphosphoryl fragments.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. C. D. Gutsche, Calixarenes, The Royal Society of Chemistry, Cambridge, 1989, 132.

    Google Scholar 

  2. J. Vicens and V. Böhmer, Calixarenes: a Versatile Class of Macrocyclic Compounds, Kluwer Acad. Publ., Dordrecht, 1991, 15.

    Google Scholar 

  3. Z. Asfari, V. Böhmer, J. Harrowfield, and J. Vicens, Calixarenes 2001, Kluwer Acad. Publ., Dordrecht-Boston-London, 2001.

    Google Scholar 

  4. R. J. Egbering, P. L. Cobben, W. Verboom, S. Harkema, and D. N. Reinhoudt, J. Inclusion Phenom., 1992, 151.

  5. L. M. Tunstad, J. A. Tucker, E. Dalcanale, J. Weiser, J. A. Bryant, J. C. Sherman, R. C. Helgeson, C. B. Knobler, and D. J. Cram, J. Org. Chem., 1989, 1305.

  6. E. U. Thoden van Velzen, J. F. Engbersen, and D. N. Reinhoudt, J. Am. Chem. Soc., 1994, 3597.

  7. V. V. Kormachev and M. S. Fedoseev, Preparativnaya khimiya fosfora [The Preparative Chemistry of Phosphorus], Uro RAS Publ., Perm, 1992, 189 (in Russian).

    Google Scholar 

  8. A.s. 883047; Byul. Izobret., 1981, No. 43.

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to M. A. Pudovik.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 1102–1106, June, 2007.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Burilov, A.R., Knyazeva, I.R., Sadykova, Y.M. et al. Synthesis of calix[4]resorcinarenes, containing phosphoryl fragments at the lower rim of the molecule. Russ Chem Bull 56, 1144–1148 (2007). https://doi.org/10.1007/s11172-007-0173-2

Download citation

  • Received:

  • Revised:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11172-007-0173-2

Key words

Navigation