Abstract
Reaction of 2,4-disubstituted phenols with paraformaldehyde in the presence of SnCl4 and 2,6-lutidine afforded a number of new salicylaldehydes, containing bulky substituents (tert-butyl, 1-phenylethyl, 1-(4-tert-butylphenyl)ethyl, α-cumyl, and trityl) in the positions 3 and 5.
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Dedicated to the memory of Academician N. N. Vorozhtsov on the 100th anniversary of his birth.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 1084–1088, June, 2007.
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Kochnev, A.I., Oleynik, I.I., Oleynik, I.V. et al. Synthesis of salicylaldehydes bearing bulky substituents in the positions 3 and 5. Russ Chem Bull 56, 1125–1129 (2007). https://doi.org/10.1007/s11172-007-0170-5
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DOI: https://doi.org/10.1007/s11172-007-0170-5