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Porphyrin models of natural catalases

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Abstract

The kinetics of H2O2 decomposition in the presence of copper complexes with porphyrins, whose structure is regularly changed, was studied by the volumetric method. The ion-molecular mechanism of the reaction was proposed on the basis of spectrophotometric analysis of the intermediates. The use of these complexes as simple models of natural catalases was shown to be promising.

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Authors and Affiliations

  1. Institute of Solutions Chemistry, Russian Academy of Sciences, 1 ul. Akademicheskaya, 153045, Ivanovo, Russian Federation

    T. N. Lomova, M. E. Klyueva & O. V. Kosareva

  2. Ivanovo State University, 39 ul. Ermaka, 153025, Ivanovo, Russian Federation

    M. V. Klyuev

Authors
  1. T. N. Lomova
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  2. M. E. Klyueva
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  3. M. V. Klyuev
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  4. O. V. Kosareva
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Correspondence to T. N. Lomova.

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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 719–724, April, 2007.

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Lomova, T.N., Klyueva, M.E., Klyuev, M.V. et al. Porphyrin models of natural catalases. Russ Chem Bull 56, 748–753 (2007). https://doi.org/10.1007/s11172-007-0112-2

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  • DOI: https://doi.org/10.1007/s11172-007-0112-2

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