Abstract
The reaction of 5-[2-(methylthio)ethyl]-3-phenyl-2-thioxoimidazolidin-4-one (LH) with salts MCl2· xH2O (M = Co, Ni, Cu; x = 2, 6) afforded the [M(L)Cl]n complexes of NiII, CoII, and CuII. The electrochemical behavior of the LH ligand and its complexes was studied using the cyclic voltammetry and rotating disk electrode techniques. The structures of the synthesized compounds were determined by the data of UV—Vis and IR spectroscopy, mass spectrometry, and electrochemical characteristics.
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S. V. Kryatov, B. S. Mohanraj, V. V. Tarasov, O. P. Kryatova, E. V. Rybak-Akimova, B. Nithakki, J. F. Rusling, R. J. Staples, and A. Y. Nazarenko, Inorg. Chem., 2002, 41, 923.
E. T. Papish, T. M. Taylor, F. E. Jernigan, M. J. Rodig, R. R. Shawhan, G. P. A. Yap, and F. A. Jove, Inorg. Chem., 2006, 45, 2242.
B. Xie, L. J. Wilson, and D. M. Stanbury, Inorg. Chem., 2001, 40, 3606.
A. G. Majouga, E. K. Beloglazkina, I. V. Yudin, N. V. Zyk, A. A. Moiseeva, and K. P. Butin, Izv. Akad. Nauk, Ser. Khim., 2005, 2099 [Russ. Chem. Bull., Int. Ed., 2005, 54, 2163].
A. G. Majouga, E. K. Beloglazkina, S. Z. Vatsadze, A. A. Moiseeva, F. S. Moiseev, K. P. Butin, and N. V. Zyk, Mendeleev Commun., 2005, 48.
E. K. Beloglazkina, S. Z. Vatsadze, A. G. Majouga, N. A. Frolova, R. B. Romashkina, N. V. Zyk, A. A. Moiseeva, and K. P. Butin, Izv. Akad. Nauk, Ser. Khim., 2005, 2679 [Russ. Chem. Bull., Int. Ed., 2005, 54, 2771].
E. K. Beloglazkina, A. G. Majouga, R. B. Romashkina, and N. V. Zyk, Tetrahedron Lett., 2006, 47, 2957.
T. Johnson and W. Scott, J. Am. Chem. Soc., 1913, 35, 1136.
M. N. S. Hill, L. Cucurull-Sanchez, J. R. Creighton, P. D. Akrivos, W. Clegg, and E. S. Raper, Inorg. Chim. Acta, 1998, 271, 57.
E. S. Raper, Coord. Chem. Rev., 1996, 153, 199.
E. S. Raper, Coord. Chem. Rev., 1997, 165, 475.
I. Kuzniarska-Biernacka, A. Bartecki, and K. Kurzak, Polyhedron, 2003, 22, 997.
F. A. Cotton and G. Wilkinson, Advanced Inorganic Chemistry, 2nd ed., J. Wiley and Sons, New York—London—Sydney, 1966.
L. Zhang, L. Liu, D. Jia, and K. Yu, Struct. Chem., 2004, 15, 327.
L. F. Larkworthy, J. T. Murphy, and D. J. Phillips, Inorg. Chem., 1968, 7, 1436.
L. F. Larkworthy, J. T. Murphy, and D. J. Phillips, Inorg. Chem., 1968, 7, 1443.
E. K. Beloglazkina, A. G. Majouga, I. V. Yudin, N. A. Frolova, N. V. Zyk, V. D. Dolzhikova, A. A. Moiseeva, R. D. Rakhimov, and K. P. Butin, Izv. Akad. Nauk, Ser. Khim., 2006, 978 [Russ. Chem. Bull., Int. Ed., 2006, 55, 1015].
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 339–343, February, 2007.
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Beloglazkina, E.K., Majouga, A.G., Moiseeva, A.A. et al. 5-[2-(Methylthio)ethyl]-3-phenyl-2-thioxoimidazolidin-4-one and its complexes with transition metals (CoII, NiII, and CuII). Synthesis and electrochemical investigation. Russ Chem Bull 56, 351–355 (2007). https://doi.org/10.1007/s11172-007-0057-5
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DOI: https://doi.org/10.1007/s11172-007-0057-5