Abstract
New phosphorylated calix[4]resorcinarene and cavitands were synthesized. Their extraction ability toward LaIII, GdIII, and YbIII ions was studied. The cavitands are more efficient extracting agents than octasubstituted calix[4]resorcinarenes. The nature of substituents at the nitrogen atom at the upper rim and hydrophobic substituents at the lower rim exerts a substantial effect on the solubility of the extracted complex in chloroform. Coordination of two lanthanide ions with an extragent molecule results in their efficient but non-selective extraction. The literature and our spectral (31P NMR) data suggested that the ligand in the extracted complex has most probably a “kite” conformation.
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 303–308, February, 2007.
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Mustafina, A.R., Zagidullina, I.Y., Maslennikova, V.I. et al. Liquid extraction of LaIII, GdIII, and YbIII ions by phosphorylated calix[4]resorcinarene derivatives. Russ Chem Bull 56, 313–319 (2007). https://doi.org/10.1007/s11172-007-0051-y
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DOI: https://doi.org/10.1007/s11172-007-0051-y