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Trisodium heptaphosphide in reactions with alkyl and aryl tosylates

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Abstract

Reactions of trisodium heptaphosphide with alkyl tosylates gave dialkylheptaphosphides or trialkylheptaphosphines, depending on the stoichiometric ratios of the starting reagents. A method for determination of the coupling constants of the asymmetric isomer of trialkyl-heptaphosphines was proposed. Reactions of the heptaphosphide trianion with aryl tosylates yielded disodium hexadecaphosphide.

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References

  1. V. A. Milyukov, Yu. G. Budnikova, and O. G. Sinyashin, Usp. Khim., 2005, 74, 859 [Russ. Chem. Rev., 2005, 74, 781 (Engl. Transl.)].

    Google Scholar 

  2. H. G. von Schnering and W. Hönle, Chem. Rev., 1988, 88, 243.

    Article  Google Scholar 

  3. M. Baudler and K. Glinka, Chem. Rev., 1993, 93, 1623.

    Article  CAS  Google Scholar 

  4. G. Fritz, K. D. Hoppe, W. Hönle, D. Weber, C. Mujica, and H.-G. von Schnering, J. Organomet. Chem., 1983, 249, 63.

    Article  CAS  Google Scholar 

  5. M. Baudler, W. Faber, and J. Hahn, Z. Anorg. Allg. Chem., 1980, 469, 15.

    Article  CAS  Google Scholar 

  6. G. Fritz and H.-W. Schneider, Z. Anorg. Allg. Chem., 1990, 584, 12.

    Article  CAS  Google Scholar 

  7. S. Charles, J. C. Fettinger, and B. W. Eichhorn, J. Am. Chem. Soc., 1995, 117, 5303.

    Article  CAS  Google Scholar 

  8. A. M. R. Gonsalves, J. C. Bayon, M. E. S. Serra, and J. P. R. Pereira, J. Organomet. Chem., 1998, 553, 199.

    Article  Google Scholar 

  9. G. Fritz, H. Rothmann, and E. Matern, Z. Anorg. Allg. Chem., 1992, 610, 33.

    Article  CAS  Google Scholar 

  10. K. Marat, SPINWORKS, Ver. 2.3, University of Manitoba, Canada, 2004.

    Google Scholar 

  11. PERCH, Ver. 1, PERCH Solutions Ltd., Kuopio (Finland), 2005.

  12. M. Baudler, R. Heumüller, and J. Hahn, Z. Anorg. Allg. Chem., 1985, 529, 7.

    Article  CAS  Google Scholar 

  13. V. A. Milyukov, A. V. Kataev, O. G. Sinyashin, and E. Hey-Hawkins, Izv. Akad. Nauk, Ser. Khim., 2006, 1249 [Russ. Chem. Bull., Int. Ed., 2006, 55, 1297].

    Google Scholar 

  14. H. Gilman and O. L. Marrs, J. Org. Chem., 1965, 30, 2096.

    Article  CAS  Google Scholar 

  15. C. H. Snyder and A. R. Sotto, J. Org. Chem., 1964, 29, 742.

    Article  CAS  Google Scholar 

  16. K. M. Davies and W. J. Hickinbottom, J. Chem. Soc., 1965, 3, 2295.

    Google Scholar 

  17. G. M. Fraser and H. M. R. Hoffman, J. Chem. Soc. B, 1967, 5, 425.

    Article  Google Scholar 

  18. D. L. Tabern and E. H. Volwiler, J. Am. Chem. Soc., 1934, 56, 1139.

    Article  CAS  Google Scholar 

  19. D. J. McLenan, J. Chem. Soc. B, 1966, 28, 705.

    Article  Google Scholar 

  20. J. M. Tedder and B. Webster, J. Chem. Soc., 1960, 11, 4417.

    Article  Google Scholar 

  21. M. Neeman, A. Modiano, and Y. Shor, J. Org. Chem., 1956, 21, 671.

    Article  CAS  Google Scholar 

  22. D. Zim, V. R. Lando, and J. Dupont, Org. Lett., 2001, 3, 3049.

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center of the Russian Academy of Sciences, 8 ul. Akad. Arbuzova, 420088, Kazan, Russian Federation

    V. A. Milyukov, A. V. Kataev & O. G. Sinyashin

  2. Institute of Inorganic Chemistry, University of Leipzig, 29 Johannisallee, D-04103, Leipzig, Germany

    E. Hey-Hawkins

Authors
  1. V. A. Milyukov
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  2. A. V. Kataev
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  3. E. Hey-Hawkins
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  4. O. G. Sinyashin
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Corresponding author

Correspondence to V. A. Milyukov.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 289–293, February, 2007.

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Milyukov, V.A., Kataev, A.V., Hey-Hawkins, E. et al. Trisodium heptaphosphide in reactions with alkyl and aryl tosylates. Russ Chem Bull 56, 298–303 (2007). https://doi.org/10.1007/s11172-007-0048-6

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  • DOI: https://doi.org/10.1007/s11172-007-0048-6

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