Abstract
Phosphorylacetic acid esters containing the menthoxy fragment at the phosphorus atom or at the carbonyl group were synthesized. The configurations of the enantiomerically pure compounds, viz., methyl (ethoxy)(menthyloxy)phosphorylacetate and menthyl [(2-chloro-ethoxy)(4-dimethylaminophenyl)phosphoryl]acetate, were established by X-ray diffraction and NMR spectroscopy.
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 281–288, February, 2007.
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Bredikhin, A.A., Eliseenkova, R.M., Tarasova, R.I. et al. Nonracemic menthyl phosphorylacetates. Russ Chem Bull 56, 290–297 (2007). https://doi.org/10.1007/s11172-007-0047-7
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DOI: https://doi.org/10.1007/s11172-007-0047-7