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Chemiluminescence during decomposition of 1,4-dimethylnaphthalene endoperoxide on the silica gel and alumina surface

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Abstract

Decomposition of 1,4-dimethylnaphthalene endoperoxide supported on the silica gel and alumina surface is accompanied by chemiluminescence (CL) in the IR and visible spectral regions. The CL emitter in the IR region is singlet oxygen. The 1O2 dimol contributes mainly to the emission at λmax = 630 and 700 nm. It was shown by the IR-CL method that endoperoxide decomposition on the sorbent surface follows the first-order kinetics. The activation parameters of the process were determined. On the Al2O3 and silica gel surfaces a substantial acceleration of the decomposition of 1,4-dimethylnaphthalene endoperoxide is observed compared to the solution.

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Authors and Affiliations

  1. Institute of Organic Chemistry, Ufa Research Center of the Russian Academy of Sciences, 71 prosp. Oktyabrya, 450054, Ufa, Russian Federation

    D. V. Kazakov, D. V. Mal’tsev, G. Ya. Maistrenko & V. P. Kazakov

  2. Department of Chemistry, Bashkir State University, 32 ul. Frunze, 450007, Ufa, Russian Federation

    S. L. Khursan & M. Yu. Ovchinnikov

Authors
  1. D. V. Kazakov
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  2. D. V. Mal’tsev
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  3. G. Ya. Maistrenko
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  4. S. L. Khursan
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  5. M. Yu. Ovchinnikov
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  6. V. P. Kazakov
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Correspondence to D. V. Kazakov.

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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 199–204, February, 2007.

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Kazakov, D.V., Mal’tsev, D.V., Maistrenko, G.Y. et al. Chemiluminescence during decomposition of 1,4-dimethylnaphthalene endoperoxide on the silica gel and alumina surface. Russ Chem Bull 56, 205–210 (2007). https://doi.org/10.1007/s11172-007-0034-z

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  • DOI: https://doi.org/10.1007/s11172-007-0034-z

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