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Unusual magnetic behavior of the new supramolecular ensemble [Ni2L4]2·[NiCl2(LH)2(MeCN)2]·4MeCN (LH is 2-mercaptobenzimidazole)

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Abstract

The diamagnetic dinuclear complex Ni2L4 was synthesized by the reaction of NiCl2·6H2O with 2-mercaptobenzimidazole (LH) in ethanol in the presence of Et3N. The solid-state reaction (reagent ratio Ni: LH = 1: 2) followed by recrystallization of the reaction product from a MeCN-THF mixture afforded crystals of the associate [Ni2L4]2·[NiCl2(LH)2(MeCN)2] containing four acetonitrile solvate molecules. Crystals of 2·4MeCN exhibit ferromagnetic properties at helium temperatures.

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References

  1. V. A. Ivanov, T. G. Aminov, V. M. Novotortsev, and V. T. Kalinnikov, Izv. Akad. Nauk, Ser. Khim., 2004, 2255 [Russ. Chem. Bull., Int. Ed., 2004, 53, 2357].

    Google Scholar 

  2. R. Z. Sagdeev and V. I. Ovcharenko, Usp. Khim., 1999, 68, 345 [Russ. Chem. Rev., 1999, 68 (Engl. Transl.)].

    Article  Google Scholar 

  3. O. Khan, Molecular Magnetism, VCH, New York, 1993.

    Google Scholar 

  4. O. Khan, Acc. Chem. Res., 2000, 33, 647.

    Article  Google Scholar 

  5. M. Verdaguer, Polyhedron, 2001, 20, 1115.

    Article  CAS  Google Scholar 

  6. V. T. Kalinnikov, Yu. V. Rakitin, and V. M. Novotortsev, Usp. Khim., 2003, 72, 995 [Russ. Chem. Rev., 2003, 72 (Engl. Transl.)].

    Article  CAS  Google Scholar 

  7. I. L. Eremenko, M. A. Golubnichaya, A. A. Sidorov, S. E. Nefedov, I. F. Golovaneva, V. I. Burkov, O. G. Ellert, V. M. Novotortsev, A. Sousa, and M. R. Bermejo, Izv. Akad. Nauk, Ser. Khim., 1998, 725 [Russ. Chem. Bull., 1998, 47, 704 (Engl. Transl.)].

    Google Scholar 

  8. I. L. Eremenko, S. E. Nefedov, A. A. Sidorov, and I. I. Moiseev, Izv. Akad. Nauk, Ser. Khim., 1999, 409 [Russ. Chem. Bull., 1999, 48, 396 (Engl. Transl.)].

    Google Scholar 

  9. I. L. Eremenko, S. E. Nefedov, A. A. Sidorov, M. A. Golubnichaya, P. V. Danilov, V. N. Ikorskii, Yu. G. Shvedenkov, V. M. Novotortsev, and I. I. Moiseev, Inorg. Chem., 1999, 38, 3764.

    Article  CAS  Google Scholar 

  10. T. B. Mikhailova, E. V. Pakhmutova, A. E. Malkov, I. F. Golovaneva, A. A. Sidorov, I. G. Fomina, G. G. Aleksandrov, V. N. Ikorskii, V. M. Novotortsev, I. L. Eremenko, and I. I. Moiseev, Izv. Akad. Nauk, Ser. Khim., 2003, 1994 [Russ. Chem. Bull., Int. Ed., 2003, 53, 2105].

    Google Scholar 

  11. A. A. Sidorov, S. M. Diamidov, S. E. Nefedov, I. G. Fomina, P. V. Danilov, V. M. Novotortsev, V. N. Ikorskii, and I. L. Eremenko, Zh. Neorg. Khim., 1999, 44, 3 [Russ. J. Inorg. Chem., 1999, 44 (Engl. Transl.)].

    Google Scholar 

  12. A. E. Malkov, I. G. Fomina, A. A. Sidorov, G. G. Aleksandrov, I. M. Egorov, N. I. Latosh, O. N. Chupakhin, Yu. V. Rakitin, G. L. Rusinov, V. M. Novotortsev, V. N. Ikorskii, and I. I. Moiseev, J. Mol. Struct., 2003, 656, 207.

    Article  CAS  Google Scholar 

  13. J. Jolley, W. I. Cross, R. G. Pritchard, C. A. McAuliffe, and K. B. Nolan, Inorg. Chim. Acta, 2001, 319, 36.

    Article  Google Scholar 

  14. Yu. V. Rakitin and V. T. Kalinnikov, Sovremennaya magnetokhimiya [Modern Magnetochemistry], Nauka, St. Petersburg, 1994 (in Russian).

    Google Scholar 

  15. G. M. Sheldrik, SADABS, Program for Scanning and Correction of Area Detector Data, Götinngen University, Götinngen, Germany, 1997.

    Google Scholar 

  16. G. M. Sheldrik, SHELX97, Program for Solution of Crystal Structures, Götinngen University, Götinngen, Germany, 1997.

    Google Scholar 

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Authors and Affiliations

  1. N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 119991, Moscow, Russian Federation

    M. E. Nikiforova, M. O. Talismanova, G. G. Aleksandrov, A. A. Sidorov, V. M. Novotortsev, I. L. Eremenko & I. I. Moiseev

  2. I. Ya. Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences, 22 ul. S. Kovalevskoi, 620219, Ekaterinburg, Russian Federation

    S. K. Kotovskaya & V. N. Charushin

  3. International Tomography Center, Siberian Branch of the Russian Academy of Sciences, 3a ul. Institutskaya, 630090, Novosibirsk, Russian Federation

    V. N. Ikorskii

Authors
  1. M. E. Nikiforova
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  2. M. O. Talismanova
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  3. G. G. Aleksandrov
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  4. S. K. Kotovskaya
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  5. A. A. Sidorov
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  6. V. M. Novotortsev
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  7. V. N. Ikorskii
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  8. V. N. Charushin
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  9. I. L. Eremenko
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  10. I. I. Moiseev
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Corresponding author

Correspondence to I. L. Eremenko.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 12, pp. 2101–2105, December, 2006.

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Nikiforova, M.E., Talismanova, M.O., Aleksandrov, G.G. et al. Unusual magnetic behavior of the new supramolecular ensemble [Ni2L4]2·[NiCl2(LH)2(MeCN)2]·4MeCN (LH is 2-mercaptobenzimidazole). Russ Chem Bull 55, 2181–2186 (2006). https://doi.org/10.1007/s11172-006-0570-y

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  • DOI: https://doi.org/10.1007/s11172-006-0570-y

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